dc.creatorHarter W.G.
dc.creatorPatterson C.W.
dc.creatorDa Paixao F.J.
dc.date1978
dc.date2015-06-30T12:52:58Z
dc.date2015-11-26T14:34:28Z
dc.date2015-06-30T12:52:58Z
dc.date2015-11-26T14:34:28Z
dc.date.accessioned2018-03-28T21:37:51Z
dc.date.available2018-03-28T21:37:51Z
dc.identifier
dc.identifierReviews Of Modern Physics. , v. 50, n. 1, p. 37 - 83, 1978.
dc.identifier346861
dc.identifier10.1103/RevModPhys.50.37
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0011001690&partnerID=40&md5=5f52e884fe6eca87781711cc63e65c69
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/97622
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/97622
dc.identifier2-s2.0-0011001690
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1248112
dc.descriptionThe theory of transformation relations between states of Born Oppenheimer and weak coupling approximations is developed for polyatomic molecules. The relations are a generalization of frame transformation relations used by Chang and Fano for symmetric-top molecules, and they lead to a more convenient symmetry labeling system than was previously available. A key internal symmetry label (named "soul") is defined so that it remains a constant label for frame transformation relations, and is conserved during vibronic transitions, ionization, and even dissociation provided the nuclear spin-rotation interaction is relatively small. Various nomograms, graphs, and tableaus associated with the soul label make it easy to predict and visualize the form of many types of complex high-resolution spectra. Simplified procedures are given for obtaining selection rules, statistical weights, and matrix elements of multipole operators for common molecules having various point symmetries. Simplifications of computational theory using the new level cluster bases for high J are discussed. © 1978 American Physical Society.
dc.description50
dc.description1
dc.description37
dc.description83
dc.languageen
dc.publisher
dc.relationReviews of Modern Physics
dc.rightsaberto
dc.sourceScopus
dc.titleFrame Transformation Relations And Multipole Transitions In Symmetric Polyatomic Molecules
dc.typeArtículos de revistas


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