Odor-active Alcohols From The Fungal Transformation Of α-farnesene

dc.creatorKrings U.
dc.creatorHardebusch B.
dc.creatorAlbert D.
dc.creatorBerger R.G.
dc.creatorMarostica Jr. M.
dc.creatorPastore G.M.
dc.date2006
dc.date2015-06-30T18:17:23Z
dc.date2015-11-26T14:29:19Z
dc.date2015-06-30T18:17:23Z
dc.date2015-11-26T14:29:19Z
dc.date.accessioned2018-03-28T21:32:32Z
dc.date.available2018-03-28T21:32:32Z
dc.identifier
dc.identifierJournal Of Agricultural And Food Chemistry. , v. 54, n. 24, p. 9079 - 9084, 2006.
dc.identifier218561
dc.identifier10.1021/jf062089j
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-33845673350&partnerID=40&md5=df8b153203709cc93ba90d69255ebf3e
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/103847
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/103847
dc.identifier2-s2.0-33845673350
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1246806
dc.descriptionSubmerged microbial cultures were screened for their potential to oxifunctionalize α-farnesene. The major oxidation product in all transforming cultures, 3,7,11-trimethyldodeca-1,3(E),5(E)10-tetraen-7-ol, showed a pleasant citrus-like odor and peak concentrations of 170 mg L -1. An Aspergillus niger isolate from mango generated another two terpene alcohols identified as diastereomeric menth-1-en-3-[2-methyl-1,3-butadienyl]-8-ol, a new natural compound with an apricot-like odor. The regiospecifity of the oxygen attack with concurrent lack of stereoselectivity suggested that the initial step of the bioconversion resembled the chemical autoxidation starting with the generation of an intermediate resonance-stabilized carbon-centered radical or carbocation. © 2006 American Chemical Society.
dc.description54
dc.description24
dc.description9079
dc.description9084
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dc.languageen
dc.publisher
dc.relationJournal of Agricultural and Food Chemistry
dc.rightsfechado
dc.sourceScopus
dc.titleOdor-active Alcohols From The Fungal Transformation Of α-farnesene
dc.typeArtículos de revistas


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