dc.creator | Alvarez V.H. | |
dc.creator | Mattedi S. | |
dc.creator | Aznar M. | |
dc.date | 2012 | |
dc.date | 2015-06-26T20:30:02Z | |
dc.date | 2015-11-26T14:26:56Z | |
dc.date | 2015-06-26T20:30:02Z | |
dc.date | 2015-11-26T14:26:56Z | |
dc.date.accessioned | 2018-03-28T21:30:01Z | |
dc.date.available | 2018-03-28T21:30:01Z | |
dc.identifier | | |
dc.identifier | Industrial And Engineering Chemistry Research. , v. 51, n. 44, p. 14543 - 14554, 2012. | |
dc.identifier | 8885885 | |
dc.identifier | 10.1021/ie302343v | |
dc.identifier | http://www.scopus.com/inward/record.url?eid=2-s2.0-84868559190&partnerID=40&md5=d0cb3209b2f418b3ffb803dd401c2334 | |
dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/97211 | |
dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/97211 | |
dc.identifier | 2-s2.0-84868559190 | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1246201 | |
dc.description | This paper reports the densities, refraction indices, and vapor liquid equilibria for binary systems ester + n-methyl-2-hydroxyethylammonium hexanoate (m-2-HEAH): methyl acetate (1) + m-2-HEAH (2), ethyl acetate (1) + m-2-HEAH, and propyl acetate (1) + m-2-HEAH (2). The excess molar volumes, deviations in the refraction index, apparent molar volume, and thermal expansion coefficient for the binary systems were fitted to polynomial equations. The Peng-Robinson equation of state, coupled with the Wong-Sandler mixing rule, is used to describe the experimental data. Since the predictive activity coefficient model COSMO-SAC is used in the Wong-Sandler mixing rule, the resulting thermodynamic model is a completely predictive one. The prediction results for the density and for the vapor-liquid equilibria have a deviation lower than 1.6% and 1.1%, respectively. © 2012 American Chemical Society. | |
dc.description | 51 | |
dc.description | 44 | |
dc.description | 14543 | |
dc.description | 14554 | |
dc.description | Huddleston, J.G., Willauer, H.D., Swatloski, R.P., Visser, A.E., Rogers, R.D., Room Temperature Ionic Liquids as Novel Media for Clean Liquid-Liquid Extraction (1998) Chem. Commun., p. 1765 | |
dc.description | Zhang, S., Zhang, Q., Zhang, Z.C., Extractive Desulfurization and Denitrogenation of Fuels Using Ionic Liquids (2004) Ind. Eng. Chem. Res., 43, p. 614 | |
dc.description | Ranu, B.C., Banerjee, S., Jana, R., Ionic Liquid as Catalyst and Solvent: The Remarkable Effect of a Basic Ionic Liquid, [bmim]OH on Michael Addition and Alkylation of Active Methylene Compounds (2007) Tetrahedron, 63, p. 776 | |
dc.description | Zhu, H.P., Yang, F., Tang, J., He, M.Y., Brønsted Acidic Ionic Liquid 1-Methylimidazolium Tetrafluoroborate: A Green Catalyst and Recyclable Medium for Esterification (2003) Green Chem., 5, p. 38 | |
dc.description | Marsh, K.N., Boxall, J.A., Lichtenthaler, R.N., Room Temperature Ionic Liquids and Their Mixtures-A Review (2004) Fluid Phase Equilib., 219, p. 93 | |
dc.description | Gabriel, S., Weiner, J., Ueber einige Abkömmlinge des Propylamins (1888) Ber. Dtsch. Chem. Ges., 21, p. 2669 | |
dc.description | Kennedy, D.F., Drummond, C.J., Large Aggregated Ions Found in Some Protic Ionic Liquids (2009) J. Phys. Chem. B., 113, p. 5690 | |
dc.description | Bicak, N., A New Ionic Liquid: 2-Hydroxyethylammonium Formate (2005) J. Mol. Liq., 116, p. 15 | |
dc.description | Greaves, T.L., Weerawardena, A., Fong, C., Krodkiewska, I., Drummond, C.J., Protic Ionic Liquids: Solvents with Tunable Phase Behavior and Physicochemical Properties (2006) J. Phys. Chem. B., 110, p. 22479 | |
dc.description | Cota, I., González-Olmos, R., Iglesias, M., Medina, F., New Short Chain Aliphatic Chain Ionic Liquids: Synthesis, Physical Properties and Catalytic Activity in Aldol Condensations (2007) J. Phys. Chem. B., 111, p. 12468 | |
dc.description | Kurnia, K., Wilfred, C., Murugesan, T., Thermophysical Properties of Hydroxyl Ammonium Ionic Liquids (2009) J. Chem. Thermodyn., 41, p. 517 | |
dc.description | Alvarez, V.H., Dosil, N., Gonzalez-Cabaleiro, R., Mattedi, S., Martin-Pastor, M., Iglesias, M., Navaza, J.M., Brønsted Ionic Liquids for Sustainable Processes: Synthesis and Physical Properties (2010) J. Chem. Eng. Data, 55, p. 625 | |
dc.description | Iglesias, M., Torres, A., González-Olmos, R., Salvatierra, D., Effect of Temperature on Mixing Thermodynamics of a New Ionic Liquid: {2-Hydroxyethylammonium Formate (2-HEAF) + Short Hydroxylic Solvents} (2008) J. Chem. Thermodyn., 40, p. 119 | |
dc.description | Sierra, J., Martí, E., Mengíbar, A., González-Olmos, R., Iglesias, M., Cruañas, R., Garau, M.A., (2008) 5th Society of Environmental Toxicology and Chemistry Congress - SETAC 2008, , Sydney, August 3-7 | |
dc.description | Peric, B., Martí, E., Sierra, J., Cruañas, R., Iglesias, M., Garau, M.A., Terrestrial Ecotoxicity of Short Aliphatic Protic Ionic Liquids (2011) Environ. Toxicol. Chem., 30, p. 2802 | |
dc.description | Peng, D., Robinson, D.B., A New Two-Constant Equation of State (1976) Ind. Eng. Chem. Fundam., 15, p. 59 | |
dc.description | Alvarez, V.H., Aznar, M., Thermodynamic Modeling of Vapor-Liquid Equilibrium of Binary Systems Ionic Liquid + Supercritical {CO 2 or CHF 3} and Ionic Liquid + Hydrocarbons Using Peng-Robinson Equation of State (2008) J. Chin. Inst. Chem. Eng., 39, p. 353 | |
dc.description | Wong, D.S.H., Sandler, S.I., A Theoretically Correct Mixing Rule for Cubic Equations of State (1992) AIChE J., 38, p. 671 | |
dc.description | Abrams, D.S., Prausnitz, J.M., Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems (1975) AIChE J., 21, p. 116 | |
dc.description | Lin, S.T., Sandler, S.I., A Priori Phase Equilibrium Prediction from a Segment Contribution Solvation Model (2002) Ind. Eng. Chem. Res., 41, p. 899 | |
dc.description | Peneloux, A., Rauzy, E., Freze, R., A Consistent Correction for Redlich-Kwong-Soave Volumes (1982) Fluid Phase Equilib., 8, p. 7 | |
dc.description | Loria, H., Pereira-Almao, P., Satyro, M., Prediction of Density and Viscosity of Bitumen Using the Peng-Robinson Equation of State (2009) Ind. Eng. Chem. Res., 48, p. 10129 | |
dc.description | Michelsen, M.L., Mollerup, J., (2007) Thermodynamic Models: Fundamentals and Computational Aspects, , Tie-Line Publications: Lyngby | |
dc.description | (2010) Accelrys Materials Studio, , http://accelrys.com/products/materials-studio/, (accessed January | |
dc.description | Mullins, E., Oldland, R., Liu, Y.A., Wang, S., Sandler, S.I., Chen, C.C., Zwolak, M., Seavey, K.C., Sigma-profile Database for Using COSMO-based Thermodynamic Methods (2006) Ind. Eng. Chem. Res., 45, p. 4389 | |
dc.description | Diedenhofen, M., Klamt, A., COSMO-RS as a Tool for Property Prediction of IL Mixtures-A Review (2010) Fluid Phase Equilib., 294, p. 31 | |
dc.description | Alvarez, V.H., Larico, R., Ianos, Y., Aznar, M., Parameter Estimation for VLE Calculation by Global Minimization: Genetic Algorithm (2008) Braz. J. Chem. Eng., 25, p. 409 | |
dc.description | Sarkar, L., Roy, M.N., Studies on Liquid-Liquid Interactions of Some Ternary Mixtures by Density, Viscosity, Ultrasonic Speed and Refraction Index Measurements (2009) Thermoch. Acta., 496, pp. 124-128 | |
dc.description | (2000) Diadem Public 1.2, , The DPPR Information and Data Evaluation Manager | |
dc.description | Sibiya, P.N., Deenadayalu, N., Excess Molar Volumes and Isentropic Compressibility of Binary Systems {Trioctylmethylammonium Bis(trifluoromethylsulfonyl)imide + Methanol or Ethanol or 1-Propanol} at Different Temperatures (2008) J. Chem. Thermodyn., 40, p. 1041 | |
dc.description | Gómez, E., González, B., Calvar, N., Domínguez, A., Excess Molar Properties of Ternary System (Ethanol + Water + 1,3-Dimethylimidazolium Methylsulphate) and its Binary Mixtures at Several Temperatures (2008) J. Chem. Thermodyn., 40, p. 1208 | |
dc.description | Alvarez, V.H., Mattedi, S., Martin-Pastor, M., Aznar, M., Iglesias, M., Thermophysical properties of binary mixtures of {ionic liquid 2-hydroxy ethylammonium acetate + (water, methanol, or ethanol)} (2011) J. Chem. Thermodynamics, 43, pp. 997-1010 | |
dc.description | Alvarez, V.H., Mattedi, S., Aznar, M., Isobaric Vapor-liquid Equilibria of 1-Ethyl-3-Methylimidazolium Ethylsulfate Plus (Propionaldehyde or Valeraldehyde): Experimental Data and Prediction (2011) J. Chem. Thermodyn., 43, p. 895 | |
dc.description | Zhong, Y., Wang, H., Diao, K., Densities and Excess Volumes of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate with Aromatic Compound at T = (298.15 to 313.15) K (2007) J. Chem. Thermodyn., 39, p. 291 | |
dc.description | Nakata, M., Sakurai, M., Refraction Index and Excess Volume for Binary Liquid Mixtures. Part 1. Analyses of New and Old Data for Binary Mixtures (1987) J. Chem. Soc. Faraday Trans., 83, p. 2449 | |
dc.description | Ruso, J.M., González-Pérez, A., Prieto, G., Sarmiento, F., A Volumetric Study of Two Related Amphiphilic Beta-Blockers as a Function of Temperature and Electrolyte Concentration (2004) Coll. Surf. B: Biointerfaces., 33, p. 165 | |
dc.description | Valderrama, J.O., Robles, P.A., Critical Properties, Normal Boiling Temperatures, and Acentric Factors of Fifty Ionic Liquids (2007) Ind. Eng. Chem. Res., 46, p. 1338 | |
dc.description | Calvar, N., González, B., Gómez, E., Dominguez, Á., Vapor-liquid Equilibria for the Ternary System Ethanol + Water +1-Ethyl-3-Methylimidazolium Ethylsulfate and the Corresponding Binary Systems Containing the Ionic Liquid at 101.3 kPa (2008) J. Chem. Eng. Data, 53, p. 820 | |
dc.language | en | |
dc.publisher | | |
dc.relation | Industrial and Engineering Chemistry Research | |
dc.rights | fechado | |
dc.source | Scopus | |
dc.title | Density, Refraction Index, And Vapor-liquid Equilibria Of N -methyl-2-hydroxyethylammonium Hexanoate Plus (methyl Acetate, Ethyl Acetate, Or Propyl Acetate) At Several Temperatures | |
dc.type | Artículos de revistas | |