Artículos de revistas
Fast And Precise Determination Of The Hydrogen Content In Hydrocarbon Mixtures By 1h Nmr [determinación Rápida Y Precisa Del Contenido De Hidrógeno En Mezclas De Hidrocarburos Por Rmn 1h]
Registro en:
Revista Colombiana De Quimica. , v. 41, n. 1, p. 7 - 30, 2012.
1202804
2-s2.0-84873472950
Autor
Avella E.
Gomez S.
Fierro Y.R.
Institución
Resumen
The results from the quantification of hydrogen content in hydrocarbon mixtures and heavy petroleum fractions by integration of the signals in their high resolution 1H NMR spectra are presented and discussed. The results show the possibility of fast and precise quantification of hydrogen in 37 structural fragments, in addition to the total hydrogen in the sample by application of unified integration intervals. In contrast to the literature procedures, the hydrogen measurement is possible with less amount of sample in solution, with low pre-scan times, d1, with no strict temperature control, without the addition of any relaxation agent, and avoiding the need of an external reference. 41 1 7 30 Speight, J.G., The chemistry and technology of petroleum (1998) New York, Marcel Dekker, pp. 216-218 (2011) Combustion Analysis, , http://www.chem.yale.edu/~chem125/125/history99/4RadicalsTypes/Analysis/Liebiganal.html, Yale University, consultado el 17 de diciembre de, Disponible en Standard Test Methods for Instrumental Determination of Carbon, Hydrogen, and Nitrogen in Petroleum Products and Lubricants (2011) Annual Book of ASTM Standards, 5 (2), pp. D5291-D5310. , DOI: 10.1520/D5291-10. ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International -IHS Custom Collections, DOI: 10.1520/D5291-10 Standard Test Method for Estimation of Hydrogen Content of Aviation Fuels (2011) Annual Book of ASTM Standards, 5 (1). , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections, DOI: 10.1520/D334305R10 D3343-05R10 Standard Test Method for Hydrogen in Petroleum Fractions (2011) Annual Book of ASTM Standards, 5 (1), pp. D1018-D1111. , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections, DOI: 10.1520/ D1018-11 Williams, R.B., Characterization of Hydrocarbons in Petroleum by Nuclear Magnetic Resonance Spectrometry (1958) ASTM. Symposium On Composition of Petroleum Oils, Determination and Evaluation, 224, pp. 168-194. , ASTM Special Technical Publication, DOI: 10.1520/STP46925S Clutter, D.R., Petrakis, L., Stenger, R.L., Jensen, R.K., Nuclear Magnetic Resonance Spectrometry of Petroleum Fractions. Carbon-13 and Proton Nuclear Magnetic Resonance Characterizations in Terms of Average Molecule Parameters (1972) Anal. Chem, 44 (8), pp. 1395-1405 Rongbao, L., Zengmin, S., Bailing, L., Structural analysis of polycy-clic aromatic hydrocarbons derived from petroleum and coal by 13C and 1H NMR Spectroscopy (1988) Fuel, 67 (4), pp. 565-569 Avella, E., Fierro, R., Intervalos de integración unifcados para la carac-terización estructural de petróleos, carbones, o sus fracciones por RMN 1H y RMN 13C (2010) Revista Colombiana De Química, 39 (1), pp. 87-109 Avella, E., (2011) Aplicación De Resonancia Magnética Nuclear Para La Caracterización De Fracciones Pesadas Del Pe-tróleo En El Proceso De Desasfaltado Por Extracción (DEMEx), Tesis De Doctorado, pp. 29-32. , Universidad Nacional de Colombia. Bogotá, 35- 49, 70, 80 (2011) ¿Qué Es ASTM International, , http://www.astm.org/FAQ/whatisastmspanish_answers.html, ASTM International, Consultado el 17 de diciembre de Standard Test Method for Hydrogen Content of Middle Distillate Petroleum Products by Low-Resolution Pulsed Nuclear Magnetic Resonance Spectroscopy (2011) Annual Book of ASTM Standards, 5 (4), pp. D7171-D7205. , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections, DOI: 10.1520/D7171-05R11 Standard Test Method for Hydrogen Content of Aviation Turbine Fuels by Low Resolution Nuclear Magnetic Resonance Spectrometry (2011) Annual Book of ASTM Standards, 5 (1). , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections, DOI: 10.1520/ D370101R06 D3701-D01R06 Standard Test Methods for Hydrogen Content of Light Distillates, Middle Distillates, Gas Oils, and Residua by Low-Resolution Nuclear Magnetic Resonance Spectroscopy (2011) Annual Book of ASTM Standards, 5 (2). , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections D4808-D01R06 Standard Test Method for Aromatic Carbon Contents of Hydrocarbon Oils by High Resolution Nuclear Magnetic Resonance Spectroscopy (2011) Annual Book of ASTM Standards, 5 (2), pp. D5292-99R09. , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections, DOI: 10.1520/D5292-99R09 Holzgrabe, U., Quantitative NMR spectroscopy in pharmaceutical applications (2010) Progress In Nuclear Magnetic Resonance Spectroscopy, 57 (2), pp. 229-240 Pauli, G.F., Jaki, B.U., Lankin, D.C., Quantitative 1H NMR: Development and Potential of a Method for Natural Products Analysis (2005) Journal of Natural Products, 68 (1), pp. 133-149 Evilia, R.F., Quantitative NMR Spectroscopy (2001) Analytical Letters, 34 (13), pp. 2227-2236 Standard Test Method for Characteristic Groups in Rubber Extender and Processing Oils and Other Petroleum-Derived Oils by the Clay-Gel Absorption Chromatographic Method (2011) Annual Book of ASTM Standards, 5 (1). , ASTM Committee D02, American Society for Testing and Materials, Englewood, ASTM International - IHS Custom Collections, DOI: 10.1520/D200703R08 D2007-D03R08 Molina, V.D., Navarro, U., Murgich, J., Partial Least-Squares (PLS) Correlation between Refned Product Yields and Physicochemical Properties with the 1H Nuclear Magnetic Resonance (NMR) Spectra of Colombian Crude Oils (2007) Energy and Fuels, 21 (3), pp. 1674-1680 Molina, V.D., Navarro, U., Murgich, J., Correlations between SARA fractions and physicochemical properties with 1H NMR spectra of vacuum residues from Colombian crude oils (2010) Fuel, 89 (1), pp. 185-192 Yang, Y., Xi, H., Liu, B., Sun, X., Zhang, T., Study on relationship bet ween the concentration of hydrocar bon groups in heavy oils and their structural parameter from 1H NMR spectra (2003) Fuel, 82 (6), pp. 721-727 Guillén, M.D., Díaz, C., Blanco, C.G., Characterization of coal tar pitches with different softening points by 1H NMR. Role of the different kinds of protons in the thermal process (1998) Fuel Processing Technology, 58 (1), pp. 1-15 Lee, S.W., Glavincevski, B., NMR method for determination of aro-matics in middle distillate oils (1999) Fuel Processing Technology, 60 (1), pp. 81-86 Bansal, V., Kapur, G.S., Sarpal, A.S., Kagdiyal, V., Jain, S.K., Srivastava, S.P., Bhatnagar, A.K., Estimation of global di-plus aromatics in Diesel-range products by NMR spectroscopy (1998) Energy and Fuels, 12 (6), pp. 1223-1227 Kapur, G.S., Singh, A.P., Sarpal, A.S., Determination of aromatics and na-phthenes in straight run gasoline by 1H NMR spectroscopy (2000) Part I. Fuel, 79 (9), pp. 1023-1029 Singh, A.P., Mukherji, S., Tiwari, A.K., Kalsi, W.R., Sarpal, A.S., Determination of benzene and total aromatics in commercial gasolines using packed column GC and NMR techniques (2003) Fuel, 82 (1), pp. 23-33 Burri, J., Crockett, R., Hany, R., Rentsch, D., Gasoline composition determined by 1H NMR spectroscopy (2004) Fuel, 83 (2), pp. 187-193 Kapur, G.S., Chopra, A., Sarpal, A.S., Estimation of total aromatic content of vacuum gas oil (VGO) fractions (370-560 oC) by 1H NMR spectroscopy (2005) Energy and Fuels, 19 (3), pp. 1065-1071 Bansal, V., Sarpal, A.S., Kapur, G.S., Sharma, V.K., Estimation of bromine number of petroleum distillates by NMR spectroscopy (2000) Energy and Fuels, 14 (5), pp. 1028-1031 Kapur, G.S., Findeisen, M., Berger, S., Analysis of hydrocarbon mixtures by diffusion-ordered NMR spectroscopy (2000) Fuel, 79 (11), pp. 1347-1351 Abu-Dagga, F., Rüegger, H., Evaluation of low boiling crude oil fractions by NMR spectroscopy. Average structural parameters and identification of aromatic components by 2D NMR spectroscopy (1988) Fuel, 67 (9), pp. 1255-1262 Meusinger, R., Gasoline analysis by 1H nuclear magnetic resonance spectroscopy (1996) Fuel, 75 (10), pp. 1235-1243 Musser, B.J., Kilpatrick, P.K., Molecular Characterization of Wax Isolated from a Variety of Crude Oils (1998) Energy and Fuels, 12 (4), pp. 715-725 Siddiqui, M.N., Ali, M.F., Investigation of chemical transformations by NMR and GPC during the laboratory aging of Arabian asphalt (1999) Fuel, 78 (12), pp. 1407-1416 Kapur, G.S., Ecker, A., Meusinger, R., Establishing Quantitative Structure-Property Relationships (QSPR) of Diesel Samples by Proton-NMR & Multiple Linear Regression (MLR) Analysis (2001) Energy and Fuels, 15 (4), pp. 943-948 Bansal, V., Vatsala, S., Kapur, G.S., Basu, B., Sarpal, A.S., Hydrocarbon-Type Analysis of Middle Distillates by Mass Spectrometry and NMR Spectroscopy Techniques - A Comparison (2004) Energy and Fuels, 18 (5), pp. 1505-1511 Bansal, V., Krishna, G.J., Chopra, A., Sarpal, A.S., Detailed Hydrocarbon Characterization of RFCC Feed Stocks by NMR Spectroscopic Techniques (2007) Energy and Fuels, 21 (2), pp. 1024-1029 Khadim, M.A., Wolny, R.A., Al-Dhuwaihi, A.S., Al-Hajri, E.A., Ghamdi, M.A., Determination of hydrogen and carbon contents in crude oil and petroleum fractions by NMR Spectroscopy (2003) The Arabian Journal For Science and Engineering, 28 (2 A), pp. 147-162 Zhao, S., Xu, Z., Xu, C.H., Chung, K.H., Wang, R., Systematic characterization of petroleum residua based on SFEF (2005) Fuel, 84 (6), pp. 635-645 Kaiser, C.R., Borges, J.L., Dos, S.A.R., Azevedo, D.A., D'Avila, L.A., Quality control of gasoline by 1H NMR: Aromatics, Olefinics, Paraffinics, and oxygenated and benzene contents (2010) Fuel, 89 (1), pp. 99-104 Nielsen, K.E., Dittmer, J., Anders Malmendal, J.A., Nielsen, N.C.H., Quantitative Analysis of Constituents in Heavy Fuel Oil by 1H Nuclear Magnetic Resonance (NMR) Spectroscopy and Multivariate Data Analysis (2008) Energy and Fuels, 22 (6), pp. 4070-4076 Bansal, V., Krishna, G.J., Singh, A.P., Gupta, A.K., Sarpal, A.S., Determination of Hydrocarbons Types and Oxygenates in Motor Gasoline: A Comparative Study by Different Analytical Techniques (2008) Energy and Fuels, 22 (1), pp. 410-415 Bakhmutov, V.I., (2004) Practical NMR Relaxation For Chemists, p. 14. , Wiltshire, John Wiley & Sons Netzel, D.A., Coover, P.T., An NMR Investigation of the chemical association and molecular dynamics in asphalt ridge tar sand ore and bitumen (1987) US Department of Energy, pp. 5-12. , Fossil Barton, W.A., Lynch, L.J., 1H NMR Spin-Lattice relaxation in Bituminous Coals (1989) Energy and Fuels, 3 (3), pp. 402-411 Andrésen, J.M., Maroto-Valer, M.M., Snape, C.E., In-situ and ambient 1H NMR relaxation measurements on thermally-treated coal and pitch (1995) ACS Proceedings of 22nd Biennial Conference ACS Held At the University of California, pp. 222-223. , San Diego. Poster Session. E4 - Student Competition: Tuesday, July 18 Dos, S.L.A.L., Pinto, A.C., San, G.R.A.S., Tavares, M.I.B., Me-sophase Formation Investigation in Pitches by NMR Relaxometry (2007) Journal of Brazilian Chemistry Society, 18 (2), pp. 255-258 Claridge, T.D.W., (2005) High-Resolution NMR Techniques In Organic Chemistry, pp. 26-27. , 2nd. reprint. Amsterdam, Elsevier, 112-115 Guedes, C.L.B., Di, M.E., de Campos, A., Mazzochin, L.F., Brag-Agnolo, G.M., de Melo, F.A., Pic-Cinato, M.T., EPR and Fluorescence Spectroscopy in the Photodegradation Study of Arabian and Colombian Crude Oils (2006) International Journal of Photoenergy, 2006 (1), pp. 1-6 Gordon, E.J., Arhju, P.H., Capacity of Petroleum Asphaltenes to Complex Heavy Metals (1963) Journal of Chemical and Engineering Data, 8 (2), pp. 252-258 Kristoforov, V.S., Study of crude oil and some of its high molecular compounds using electron paramagnetic resonance (Review) (1971) Chemistry and Technology of Fuels and Oils, 7 (8), pp. 629-631