Synergistic Effect Of Iron And Copper Oxides Supported On Silica In The Room Temperature Oxidation Of Cyclohexane

dc.creatorSchuchardt U.
dc.creatorPereira R.
dc.creatorKrahembuhl C.E.Z.
dc.creatorRufo M.
dc.creatorBuffon R.
dc.date1995
dc.date2015-06-26T17:14:49Z
dc.date2015-11-26T14:20:50Z
dc.date2015-06-26T17:14:49Z
dc.date2015-11-26T14:20:50Z
dc.date.accessioned2018-03-28T21:22:31Z
dc.date.available2018-03-28T21:22:31Z
dc.identifier
dc.identifierApplied Catalysis A, General. , v. 131, n. 1, p. 135 - 141, 1995.
dc.identifier0926860X
dc.identifier10.1016/0926-860X(95)00132-8
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0005149688&partnerID=40&md5=82425b3d20372b34f2dd4dc22afb4e78
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/96015
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/96015
dc.identifier2-s2.0-0005149688
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1244355
dc.descriptionThe room temperature oxidation of cyclohexane with oxygen/zinc (GifIV system), catalysed by iron oxide supported on silica, has been studied. It was found that after calcination the iron catalyst does not leach and is very active for oxidation. Using 4 mmol of iron chloride per 0.1 g of silica, cyclohexanone and cyclohexanol (2:1 ratio) were obtained with a turnover number of 425. Substitution of half of the iron used for impregnation by copper chloride increased the turnover number to 885, without changing the product ratio. As copper chloride alone is not active for this reaction, it exhibits a synergistic effect on the iron(III) heterogenized on the silica. © 1995 Elsevier Science B.V. All rights reserved.
dc.description131
dc.description1
dc.description135
dc.description141
dc.descriptionBarton, Doller, (1992) Acc. Chem. Res., 25, p. 504
dc.descriptionSchuchardt, Mano, (1990) Stud. Surf. Sci. Catal., 55, pp. 185-194
dc.descriptionSchuchardt, Krähembühl, Carvalho, (1991) New J. Chem., 15, p. 955
dc.descriptionIngold, (1989) Aldrichim. Acta, 22, p. 69
dc.descriptionSchuchardt, Krähembühl, Carvalho, (1994) Stud. Surf. Sci. Catal., 82, pp. 647-652
dc.descriptionBarton, Csuhai, Doller, Geletii, (1991) Tetrahedron, 47, p. 6561
dc.descriptionSchuchardt, Carvalho, Pereira, Spinacé, (1993) The Activation of Dioxygen and Homogeneous Catalytic Oxidation, pp. 243-255. , D.H.R. Barton, A.E. Martell, D.T. Sawyer, Plenum Press, New York
dc.descriptionPereira, Schuchardt, Proceedings of the 7th Brazilian Seminar on Catalysis (1993) Proceedings of the 7th Brazilian Seminar on Catalysis, pp. 135-143. , IBP-CAT, Rio de Janeiro
dc.descriptionPereira, Rufo, Schuchardt, Copper(II) Catalyzed Oxidation of Cyclohexane by tert-Butyl Hydroperoxide (1994) Journal Of The Brazilian Chemical Society, 5, p. 83
dc.descriptionLee, Kim, Jun, Shim, (1993) New J. Chem., 17, p. 409
dc.descriptionSantos, Schuchardt, (1995) J. Braz. Chem. Soc., 6. , in press
dc.descriptionSchuchardt, Spinacé, Mano, (1991) Stud. Surf. Sci. Catal., 66, pp. 47-54
dc.descriptionBarton, Boivin, Gastiger, Morzycki, Hay-Motherwell, Motherwell, Ozbalik, Schwartzentruber, J. Chem. Soc. (1986) J. Chem. Soc., p. 947. , Perkin Trans. 1
dc.descriptionSheldon, Kochi, (1981) Metal-Catalysed Oxidations of Organic Compounds, p. 250. , 2nd ed., Accademic Press, New York
dc.descriptionSchuchardt, Carvalho, Spinacé, Why is it Interesting to Study Cyclohexane Oxidation? (1993) Synlett, p. 713
dc.descriptionSheldon, Kochi, (1981) Metal-Catalysed Oxidations of Organic Compounds, p. 242. , 2nd ed., Accademic Press, New York
dc.languageen
dc.publisher
dc.relationApplied Catalysis A, General
dc.rightsfechado
dc.sourceScopus
dc.titleSynergistic Effect Of Iron And Copper Oxides Supported On Silica In The Room Temperature Oxidation Of Cyclohexane
dc.typeArtículos de revistas


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