dc.creatorKleiman G.G.
dc.creatorLanders R.
dc.creatorde Castro S.G.C.
dc.date1995
dc.date2015-06-26T17:14:21Z
dc.date2015-11-26T14:20:16Z
dc.date2015-06-26T17:14:21Z
dc.date2015-11-26T14:20:16Z
dc.date.accessioned2018-03-28T21:21:54Z
dc.date.available2018-03-28T21:21:54Z
dc.identifier
dc.identifierJournal Of Electron Spectroscopy And Related Phenomena. , v. 72, n. C, p. 199 - 203, 1995.
dc.identifier3682048
dc.identifier10.1016/0368-2048(94)02325-5
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0011249693&partnerID=40&md5=afb89c12f0c286e514f94e0c866b56b9
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/95883
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/95883
dc.identifier2-s2.0-0011249693
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1244193
dc.descriptionUnderstanding the nature of core hole screening is fundamental for interpretation of the results of electron spectroscopies of metals and alloys. The idea of complete screening of the core hole explains a large amount of XPS and high resolution Auger (XAES) data. Here, we address the question of the extent to which the complete screening model can be used to extract quantitative information about the electronic structure of metals and their alloys from measured Auger energies. Starting from general considerations, analysis of Auger parameter data illuminates the screening process throughout the 4d and 5d series, including the consequences of closing the d valence shell; the observed systematics are faithfully reproduced, quantitatively as well as qualitatively, in the 3d series as well; and parameters of a simple model consistent with complete screening which are extracted from the Auger parameter data are applicable to analysis of XPS and Auger shifts in alloys. Similar treatment of core level Auger shift data of the noble metal component in bimetallic alloys indicates the relation between the measured shifts, the relative Fermi energy (a usually unknown quantity involved in binding energy shifts) and the charge transfer. Consideration of various alloys (AuPd, CuPd, AgPd, AuCu, AuAg, and CuPt) implies a very small charge transfer and a unique determination of the relative Fermi energy. Use of noble metals as "impurities" in trimetallic alloys bears out these conclusions regarding charge transfer and Fermi energies. © 1995.
dc.description72
dc.descriptionC
dc.description199
dc.description203
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dc.languageen
dc.publisher
dc.relationJournal of Electron Spectroscopy and Related Phenomena
dc.rightsfechado
dc.sourceScopus
dc.titleCore Hole Screening And Electronic Structure Information
dc.typeArtículos de revistas


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