dc.creatorStein E.
dc.creatorFujiwara F.Y.
dc.date1996
dc.date2015-06-26T17:03:43Z
dc.date2015-11-26T14:19:07Z
dc.date2015-06-26T17:03:43Z
dc.date2015-11-26T14:19:07Z
dc.date.accessioned2018-03-28T21:20:30Z
dc.date.available2018-03-28T21:20:30Z
dc.identifier
dc.identifierJournal Of Organometallic Chemistry. , v. 525, n. 1-2, p. 31 - 37, 1996.
dc.identifier0022328X
dc.identifier
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0030588890&partnerID=40&md5=06012c3941f375d97eaceea0241ee3d9
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/95637
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/95637
dc.identifier2-s2.0-0030588890
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1243839
dc.descriptionThe reactions of [Fe3(CO)12] with the bidentate phosphines 1,2-bis(diphenylphosphino)ethane (dppe), 1,4-bis(diphenylphosphino)butane (dppb), 1,1′-bis(diphenylphosphino)ferrocene (dppf) and 1,4-bis(diphenylphosphino)benzene (dppbz) using trimethylamine N-oxide as decarbonylating agent produce the chelated [Fe3(CO)8(μ-CO)2(μ,η2-diphosphine)] and the new series of symmetrical [{Fe3(CO)9(μ,-CO)2}2(μ,η2-diphosphine)] and unsymmetrical [Fe3(CO)9(μ-CO)2](μ,η2-diphosphine)[Fe(CO)4] bridged complexes, in reasonable yield. The complexes were characterized by IR, 31P and 13C NMR spectroscopy, and elemental analysis. Electrochemical studies on these compounds reveal that the substitution of one or more phosphine ligands for carbon monoxide of [Fe3(CO)12] results in a more cathodic potential for the first reduction peak, but is insensitive to the σ-donor capabilities of the ligands.
dc.description525
dc.description1-2
dc.description31
dc.description37
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dc.languageen
dc.publisher
dc.relationJournal of Organometallic Chemistry
dc.rightsfechado
dc.sourceScopus
dc.titleReaction Of [fe3(co)12] With Bidentate Phosphines: Redox Behavior Of Products
dc.typeArtículos de revistas


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