Corrosion Resistance Of 2024 Aluminum Alloy Coated With Plasma Deposited A-c:h:si:o Films

dc.creatorMascagni D.B.T.
dc.creatorDe Souza M.E.P.
dc.creatorDe Alvarenga Freire C.M.
dc.creatorSilva S.L.
dc.creatorDe Cassia Cipriano Rangel R.
dc.creatorDa Cruz N.C.
dc.creatorRangel E.C.
dc.date2014
dc.date2015-06-25T17:52:42Z
dc.date2015-11-26T14:19:05Z
dc.date2015-06-25T17:52:42Z
dc.date2015-11-26T14:19:05Z
dc.date.accessioned2018-03-28T21:20:28Z
dc.date.available2018-03-28T21:20:28Z
dc.identifier
dc.identifierMaterials Research. Universidade Federal De Sao Carlos, v. 17, n. 6, p. 1449 - 1465, 2014.
dc.identifier15161439
dc.identifier10.1590/1516-1439.289014
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84922827905&partnerID=40&md5=9853a8d27b3e39ad648c87136ca7b6da
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/86318
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/86318
dc.identifier2-s2.0-84922827905
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1243830
dc.descriptionAA 2024 aluminum alloy is widely employed in aeronautic and automobilist industries. Its hardness and low density are attractive properties for such industrial areas. However, since it contains copper, it undergoes severe corrosion in aggressive media as saline or low Earth orbit environments. In this work, it was investigated the properties of films deposited by PECVD on AA 2024 aluminum alloy as well as the corrosion resistance of the film/substrate systems under different corrosive atmospheres. Films were prepared in a plasma atmosphere composed of 50% of oxygen and 50% of hexamethyldisiloxane resulting in a total gas pressure of 4.0 Pa. Plasma ignition was promoted by the application of radiofrequency signal (13.56 MHz) to the sample holder while grounding the topmost electrode. The plasma excitation power, P, was changed from 10 to 80 W in the six different set of experiments. Film thickness, measured by profilometer, increases by 5 times as P was elevated from 10 to 80 W. As demonstrated by the infrared spectra of the samples, films are essentially organosilicons with preservation of functional groups of the precursor molecule and with creation of different ones. The oxide proportion and the structure crosslinking degree are affected by the plasma excitation power. According to the results obtained by sessile drop technique, hydrophilic to moderately hydrophobic films are produced with changing P from 10 to 80 W. The corrosion resistance, evaluated by salt spray and electrochemical impedance spectroscopy, EIS, experiments, in general increases after film deposition. It is demonstrated that film deposition improves, in up to 36 times, the resistance of the alloy to salt spray attack. It is also shown an improvement of about 240 times in the alloy resistance under NaCl solution by the EIS data. Micrographs acquired by Scanning Electron Microscopy after the corrosion tests furnish further information on the importance of the layer physical stability on its barrier properties. Furthermore, films highly protect the alloy against the oxygen attack. Interpretations are proposed based on the modification of the plasma kinetics with P, altering film structure, composition and properties.
dc.description17
dc.description6
dc.description1449
dc.description1465
dc.descriptionSchneider, O., Kelly, R.G., Localized coating failure of epoxycoated aluminium alloy 2024-T3 in 0.5M NaCl solutions: Correlation between coating degradation, blister formation and local chemistry within blisters (2007) Corrosion Science., 49 (2), pp. 594-619. , http://dx.doi.org/10.1016/j.corsci.2006.06.006
dc.descriptionFonseca, I.T., Lima, N., Rodrigues, J.A., Pereira, M.I.S., Salvador, J.C.S., Ferreira, M.G.S., Passivity breakdown of Al 2024-T3 alloy in chloride solutions: A test of the point defect model (2002) Electrochemistry Communications., 4 (5), pp. 353-357. , http://dx.doi.org/10.1016/S1388-2481(02)00273-4
dc.descriptionCampestrini, P., Van Westing, E.P.M., Hovestad, A., De Wit, J.H.W., Investigation of the chromate conversion coating on Alclad 2024 aluminium alloy: Effect of the pH of the chromate bath (2002) Electrochimica Acta., 47 (7), pp. 1097-1113. , http://dx.doi.org/10.1016/S0013-4686(01)00818-0
dc.descriptionChan, Y., Yu, Q., Electrochemical characterization of plasma polymer coatings in corrosion protection of aluminum alloys (2005) Journal of Vacuum Science & Technology. A, Vacuum, Surfaces, and Films., 23 (4), p. 991. , http://dx.doi.org/10.1116/1.1924716
dc.descriptionAzioune, A., Marcozzi, M., Revello, V., Pireaux, J.-J., Deposition of polysiloxane-like nanofilms onto an aluminium alloy by plasma polymerized hexamethyldisiloxane: Characterization by XPS and contact angle measurements (2007) Surface and Interface Analysis., 39 (7), pp. 615-623. , http://dx.doi.org/10.1002/sia.2563
dc.descriptionDomingues, L., Oliveira, C., Fernandes, J.C.S., Ferreira, M.G.S., EIS on plasma-polymerised coatings used as pre-treatment for aluminium alloys (2002) Electrochimica Acta., 47 (13-14), pp. 2253-2258. , http://dx.doi.org/10.1016/S0013-4686(02)00064-6
dc.descriptionFanelli, F., D'Agostino, R., Fracassi, F., GC-MS investigation of hexamethyldisiloxane-oxygen fed cold plasmas: Low pressure versus atmospheric pressure operation (2011) Plasma Processes and Polymers., 8 (10), pp. 932-941. , http://dx.doi.org/10.1002/ppap.201000201
dc.descriptionChaiwong, C., Rachtanapun, P., Sarapirom, S., Boonyawan, D., Plasma polymerization of hexamethyldisiloxane: Investigation of the effect of carrier gas related to the film properties (2013) Surface and Coatings Technology., 229, pp. 12-17. , http://dx.doi.org/10.1016/j.surfcoat.2012.08.058
dc.descriptionPatel, R.P., Wolden, C.A., Plasma-enhanced chemical vapor deposition synthesis of silica-silicone nanolaminates using a single precursor (2011) Journal of Vacuum Science & Technology A, Vacuum, Surfaces, and Films., 29 (2), p. 021012. , http://dx.doi.org/10.1116/1.3553149
dc.descriptionBentez, F., Martnez, E., Esteve, J., Improvement of hardness in plasma polymerized hexamethyldisiloxane coatings by silicalike surface modification (2000) Thin Solid Films., 377-378, pp. 109-114. , http://dx.doi.org/10.1016/S0040-6090(00)01393-6
dc.descriptionLee, S.H., Lee, D.C., Preparation and characterization of thin films by plasma polymerization of hexamethyldisiloxane (1998) Thin Solid Films., 325 (1-2), pp. 83-86. , http://dx.doi.org/10.1016/S0040-6090(98)00492-1
dc.descriptionRangel, R.C.C., Souza, M.E.P., Schreiner, W.H., Freire, C.M.A., Rangel, E.C., Cruz, N.C., Effect of the fluorination of DLC film on the corrosion protection of aluminum alloy (AA 5052 (2010) Surface and Coatings Technology., 204 (18-19), pp. 3022-3028. , http://dx.doi.org/10.1016/j.surfcoat.2010.03.055
dc.descriptionHadinata, S.-S., Lee, M.-T., Pan, S.-J., Tsai, W.-T., Tai, C.-Y., Shih, C.-F., Electrochemical performances of diamond-like carbon coatings on carbon steel, stainless steel, and brass (2013) Thin Solid Films., 529, pp. 412-416. , http://dx.doi.org/10.1016/j.tsf.2012.05.041
dc.descriptionFernandes, J.C.S., Ferreira, M.G.S., Haddow, D.B., Goruppa, A., Short, R., Dixon, D.G., Plasma-polymerised coatings used as pre-treatment for aluminium alloys (2002) Surface and Coatings Technology., 154 (1), pp. 8-13. , http://dx.doi.org/10.1016/S0257-8972(01)01705-4
dc.descriptionRangel, R.C.C., Pompeu, T.C., Barros, J.L.S., Jr., Antonio, C.A., Santos, N.M., Pelici, B.O., Improvement of the corrosion resistance of carbon steel by plasma deposited thin films (2012) Recent Researches in Corrosion Evaluation and Protection, pp. 91-116. , http://dx.doi.org/10.5772/34623, In Razavi RS, editor. Rijeka: InTech Europe
dc.descriptionYasuda, H.K., (1985) Plasma Polymerization, , New York Academic Press
dc.descriptionCatherine, Y., Couderc, P., Electrical characteristics and growth kinetics in discharges used for plasma deposition of amorphous carbon (1986) Thin Solid Films., 144 (2), pp. 265-280. , http://dx.doi.org/10.1016/0040-6090(86)90419-0
dc.descriptionEsch, S., Bott, M., Michely, T., Comsa, G., Nucleation of homoepitaxial films grown with ion assistance on Pt (111) (1995) Applied Physics Letters., 67 (21), p. 3209. , http://dx.doi.org/10.1063/1.115165
dc.descriptionRicci, M., Dorier, J.-L., Hollenstein, C., Fayet, P., Influence of argon and nitrogen admixture in HMDSO/O2 plasmas onto powder formation (2011) Plasma Processes and Polymers., 8 (2), pp. 108-117. , http://dx.doi.org/10.1002/ppap.201000052
dc.descriptionMontarsolo, A., Mossotti, R., Innocenti, R., Vassallo, E., A study on washing resistance of pp-HMDSO films deposited on wool fabrics for anti-pilling purposes (2013) Surface and Coatings Technology., 224, pp. 109-113. , http://dx.doi.org/10.1016/j.surfcoat.2013.03.007
dc.descriptionKo, Y.-M., Choe, H.-C., Jung, S.-C., Kim, B.-H., Plasma deposition of a silicone-like layer for the corrosion protection of magnesium (2013) Progress in Organic Coatings., 76 (12), pp. 1827-1832. , http://dx.doi.org/10.1016/j.porgcoat.2013.05.024
dc.descriptionGengenbach, T.R., Griesser, H.J., Post-deposition ageing reactions differ markedly between plasma polymers deposited from siloxane and silazane monomers (1999) Polymer., 40 (18), pp. 5079-5094. , http://dx.doi.org/10.1016/S0032-3861(98)00727-7
dc.descriptionKurosawa, S., Choi, B.-G., Park, J.-W., Aizawa, H., Shim, K.-B., Yamamoto, K., Synthesis and characterization of plasma-polymerized hexamethyldisiloxane films (2006) Thin Solid Films., 506-507, pp. 176-179. , http://dx.doi.org/10.1016/j.tsf.2005.08.210
dc.descriptionPetasch, W., Baumgärtner, K., Räuchle, E., Walker, M., Influence of plasma surface treatment on the adhesion of thin films on metals (1993) Surface and Coatings Technology., 59 (1-3), pp. 301-305. , http://dx.doi.org/10.1016/0257-897293)90101-S
dc.descriptionWavhal, D.S., Zhang, J., Steen, M.L., Fisher, E.R., Investigation of gas phase species and deposition of SiO2 films from HMDSO/O2 plasmas (2006) Plasma Processes and Polymers., 3 (3), pp. 276-287. , http://dx.doi.org/10.1002/ppap.200500140
dc.descriptionCasserly, T.B., Gleason, K.K., Chemical vapor deposition of organosilicon thin films from methylmethoxysilanes (2005) Plasma Processes and Polymers., 2 (9), pp. 679-687. , http://dx.doi.org/10.1002/ppap.200500055
dc.descriptionCoclite, A.M., Milella, A., Palumbo, F., Fracassi, F., D'Agostino, R., Chemical and morphological characterization of low-k dielectric films deposited from hexamethyldisiloxane and ethylene RF glow discharges (2010) Plasma Processes and Polymers., 7 (12), pp. 1022-1029. , http://dx.doi.org/10.1002/ppap.201000091
dc.descriptionBouteau, M., Cantin, S., Fichet, O., Perrot, F., Teyssié, D., Contribution toward comprehension of contact angle values on single polydimethylsiloxane and poly(ethylene oxide) polymer networks (2010) Langmuir., 26 (22), pp. 17427-17434. , http://dx.doi.org/10.1021/la102384s, PMid:20919692
dc.descriptionBruce, R.L., Lin, T., Phaneuf, R.J., Oehrlein, G.S., Bell, W., Long, B., Molecular structure effects on dry etching behavior of Si-containing resists in oxygen plasma (2010) Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures., 28 (4), p. 751. , http://dx.doi.org/10.1116/1.3455496
dc.descriptionMansfeld, F., Recording and analysis of AC impedance data for corrosion studies (1981) Corrosion., 37 (5), pp. 301-307. , http://dx.doi.org/10.5006/1.3621688
dc.descriptionHuda, Z., Taib, N.I., Zaharinie, T., Characterization of 2024-T3: An aerospace aluminum alloy (2009) Materials Chemistry and Physics., 113 (2-3), pp. 515-517. , http://dx.doi.org/10.1016/j.matchemphys.2008.09.050
dc.descriptionTrasferetti, B.C., Davanzo, C.U., De Bica Moraes, M.A., Infrared and raman studies on films of organosiloxane networks produced by PECVD (2004) Macromolecules., 37 (2), pp. 459-466. , http://dx.doi.org/10.1021/ma035297a
dc.languageen
dc.publisherUniversidade Federal de Sao Carlos
dc.relationMaterials Research
dc.rightsaberto
dc.sourceScopus
dc.titleCorrosion Resistance Of 2024 Aluminum Alloy Coated With Plasma Deposited A-c:h:si:o Films
dc.typeActas de congresos


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