Actas de congresos
Thermodynamics Of Binary Liquid Mixtures: Application Of The Prigogine-flory-patterson Theory To Excess Molar Volumes Of Acetonitrile + 1-alkanol Systems
Registro en:
Journal Of Molecular Liquids. , v. 110, n. 1-3, p. 81 - 85, 2004.
1677322
10.1016/S0167-7322(03)00235-6
2-s2.0-1042269697
Autor
Torres R.B.
Francesconi A.Z.
Volpe P.L.O.
Institución
Resumen
Excess molar volumes of {(1-x A)CH 3(CH 2) n-1OH+x ACH 3CN} for n=1, 2, 3 or 4 as a function of composition under atmospheric pressure at 288.15, 293.15, 298.15 and 303.15 K have been used to test the applicability of the Prigogine-Flory-Patterson theory. According to the model, interactional contribution is the most important one to explain the V m E behavior. Good agreement is only achieved for the mixtures containing methanol (C 1) or 1-butanol (C 4). For the mixtures containing ethanol (C 2) and 1-propanol (C 3), which show an S-shaped V m E behavior, the correlation fails. © 2003 Elsevier B.V. All rights reserved. 110 1-3 81 85 Flory, P.J., Orwoll, R.A., Vrij, A., (1964) J. Am. Chem. Soc., 86, p. 3507 Flory, P.J., Orwoll, R.A., Vrij, A., (1964) J. Am. Chem. Soc., 86, p. 3515 Flory, P.J., (1833) J. Am. Chem. Soc., 87, p. 1965 Abe, A., Flory, P.J., (1838) J. Am. Chem. Soc., 87, p. 1965 Orwoll, R.A., Flory, P.J., (1967) J. Am. Chem. Soc., 89, p. 6814 Orwoll, R.A., Flory, P.J., (1967) J. Am. Chem. Soc., 89, p. 6822 Prigogine, I., (1957) The Molecular Theory of Solution, , Amsterdam: North Holland Prigogine, I., Trappeniers, N., Mathot, V., (1953) Dis. Faraday Soc., 15, p. 93 Prigogine, I., Trappeniers, N., Mathot, V., (1953) J. Chem. Phys., 25, p. 559 Letcher, T.M., Perkins, D.M., (1984) Thermochim. Acta, 77, p. 267 Letcher, T.M., Baxter, R.C., (1987) J. Chem. Thermodyn., 19, p. 321 Jones, D.E.G., Weeks, I.A., Benson, G.C., (1971) Can. J. Chem., 49, p. 2481 Fujihara, I., Kobayashi, M., Murakami, S., (1983) Fluid Phase Equilibr., 15, p. 81 Patterson, D., Delmas, G., (1970) Dis. Faraday Soc., 49, p. 98 Barbe, M., Patterson, D., (1980) J. Solution Chem., 9, p. 753 Van, H.T., Patterson, D., (1984) J. Solution Chem., 11, p. 793 Costas, M., Patterson, D., (1984) J. Solution Chem., 11, p. 807 Tôrres, R.B., Francesconi, A.Z., (2003) J. Mol. Liquids, 103-104, p. 99 Tôrres, R.B., Pina, C.G., Francesconi, A.Z., (2003) J. Mol. Liquids, 107 (1-3), p. 127 Oswal, S.L., Maisuria, M.M., (2002) J. Mol. Liquids, 100, p. 91 Letcher, T.M., Moollan, W.C., Nevines, J.A., Dománska, U., (2000) J. Chem. Thermodyn., 32, p. 579 Dománska, U., Lachwa, J., (2000) J. Chem. Thermodyn., 32, p. 857 Sastry, N.V., Patel, S.R., Prosad, D.H.L., (2000) Thermochim. Acta, 359, p. 169 Brocos, P., Amigo, A., Pintos, M., Calvo, E., Bravo, R., (1996) Thermochim. Acta, 286, p. 297 Mehta, S.K., Chauhan, R.K., Dewan, R.K., (1996) J. Chem. Soc. Faraday Trans., 92, p. 1167 Estaquio-Rincón, R., Trejo, A., (1994) J. Chem. Soc. Faraday Trans., 90, p. 113 Patel, S.G., Oswal, S.L., (1992) J. Chem. Soc. Faraday Trans., 88, p. 2497 Kasprzyck-Guttman, T., Kurcińska, H., (1989) J. Solution Chem., 18, p. 727 Dewan, R.K., Sharma, A.K., Mehta, S.K., (1988) J. Solution Chem., 17, p. 459 Sharma, S.C., Joshi, I.M., Singh, J., Gupta, A., (1992) J. Solution Chem., 21, p. 289 Letcher, T.M., Baxter, R.C., (1989) J. Solution Chem., 18, p. 65 Letcher, T.M., Baxter, R.C., (1989) J. Solution Chem., 18, p. 81 Letcher, T.M., Baxter, R.C., (1989) J. Solution Chem., 18, p. 89 Awwad, A.M., Jbara, K.A., Al-Dujaili, A.H., (1988) Fluid Phase Equilibr., 41, p. 277 Awwad, A.M., Jbara, K.A., Al-Dujaili, A.H., (1989) Fluid Phase Equilibr., 47, p. 95 Pina, C.G., Francesconi, A.Z., (1998) Fluid Phase Equilibr., 143, p. 143 Tôrres, R.B., Francesconi, A.Z., Volpe, P.L.O., (2002) Fluid Phase Equilibr., 200, p. 1 Tôrres, R.B., Francesconi, A.Z., (2002) Fluid Phase Equilibr., 200, p. 317 Tôrres, R.B., Francesconi, A.Z., Volpe, P.L.O., (2003) Fluid Phase Equilibr., 210, p. 287 Cibulka, I., Hynek, V., Holub, R., Pick, J., (1979) Collect. Czech. Chem. Commun., 47, p. 295 Cibulka, I., Nguyen, V.D., Holub, R., (1984) J. Chem. Thermodyn., 16, p. 159 Nakanishi, K., Shirai, H., (1970) Bull. Chem. Soc. Jpn., 43, p. 1635 Narayanaswamy, G., Dharmaraju, G., Raman, G.K., (1981) J. Chem. Thermodyn., 13, p. 327 Dewan, R.K., Mehta, K., (1986) J. Chem. Thermodyn., 18, p. 101 Sandhu, R.J.S., Sharma, A.K., Wadl, R.K., (1986) J. Chem. Eng. Data, 31, p. 152 Funke, H., Wetzel, M., Heintz, A., (1989) Pure Appl. Chem., 61, p. 1429 Bender, M., Heintz, A., (1993) Fluid Phase Equilibr., 89, p. 197 Kammerer, K., Lichtenthaler, R.N., (1998) Thermochim. Acta, 310, p. 61