Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH

dc.creatorDias, Luiz C.
dc.creatorCampano, Priscila L.
dc.date1998-02-01
dc.date2014-07-17T17:17:58Z
dc.date2015-11-26T11:48:05Z
dc.date2014-07-17T17:17:58Z
dc.date2015-11-26T11:48:05Z
dc.date.accessioned2018-03-28T20:51:41Z
dc.date.available2018-03-28T20:51:41Z
dc.identifierJournal of the Brazilian Chemical Society. Sociedade Brasileira de Química, v. 9, n. 1, p. 97-99, 1998.
dc.identifier0103-5053
dc.identifierS0103-50531998000100017
dc.identifier10.1590/S0103-50531998000100017
dc.identifierhttp://dx.doi.org/10.1590/S0103-50531998000100017
dc.identifierhttp://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100017
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/25084
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/25084
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1236515
dc.descriptionA series of a,b-unsaturated alkyl and aryl ketones, esters and N-methoxy-N-methyl-amides (Weinreb amides) containing an O-benzyl protecting group undergo conjugate reduction by H2/Pd/C in the presence of 2N NH4OH/MeOH at room temperature and ordinary pressure leaving the benzyl group intact
dc.descriptionUma série de alquil e aril cetonas, ésteres e N-metóxi-N-metil amidas (Amidas de Weinreb) alfa,beta-insaturadas contendo um grupo protetor O-benzyl sofrem redução conjugada por H2/Pd/C na presença de solução 2N de NH4OH/MeOH a temperatura ambiente e pressão normal deixando o grupo benzil intacto.
dc.description97
dc.description99
dc.languageen
dc.publisherSociedade Brasileira de Química
dc.relationJournal of the Brazilian Chemical Society
dc.rightsaberto
dc.sourceSciELO
dc.subjectconjugate reduction
dc.subjectinhibition of benzyl ether hydrogenolysis
dc.subjectchemoselective reduction of alpha
dc.subjectbeta-unsaturated compounds
dc.subjectselective catalytic hydrogenation
dc.titleConjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
dc.typeArtículos de revistas


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