dc.creator | Harris, Maria Inês N. C. | |
dc.creator | Braga, Antonio C. H. | |
dc.date | 2004-12-01 | |
dc.date | 2014-07-17T17:20:01Z | |
dc.date | 2015-11-26T11:46:56Z | |
dc.date | 2014-07-17T17:20:01Z | |
dc.date | 2015-11-26T11:46:56Z | |
dc.date.accessioned | 2018-03-28T20:50:36Z | |
dc.date.available | 2018-03-28T20:50:36Z | |
dc.identifier | Journal of the Brazilian Chemical Society. Sociedade Brasileira de Química, v. 15, n. 6, p. 971-975, 2004. | |
dc.identifier | 0103-5053 | |
dc.identifier | S0103-50532004000600027 | |
dc.identifier | 10.1590/S0103-50532004000600027 | |
dc.identifier | http://dx.doi.org/10.1590/S0103-50532004000600027 | |
dc.identifier | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000600027 | |
dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/25199 | |
dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/25199 | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1236231 | |
dc.description | Reduction of beta-enamino ketones 2 with NaBH4 in glacial acetic acid gave gamma-amino alcohols 1 in 70% to 98% yield with diastereomeric excesses, preferentially the syn product, from 44% to 90%. The stereochemistry of these compounds was confirmed by analysis of their tetrahydro-1,3-oxazine derivatives 3. | |
dc.description | A redução de beta-enamino cetonas 2 com NaBH4 em ácido acético glacial produziu gama-amino álcoois 1 em 70% a 98% de rendimento, com excessos diastereoméricos, preferencialmente o produto syn, de 44% a 90%. A estereoquímica desses compostos foi confirmada pela análise de seus derivados tetraidro-1,3-oxazinas 3. | |
dc.description | 971 | |
dc.description | 975 | |
dc.language | en | |
dc.publisher | Sociedade Brasileira de Química | |
dc.relation | Journal of the Brazilian Chemical Society | |
dc.rights | aberto | |
dc.source | SciELO | |
dc.subject | amino alcohols | |
dc.subject | enamino ketones | |
dc.subject | oxazines | |
dc.subject | stereoselective reduction | |
dc.title | An easy and efficient method to produce gamma-amino alcohols by reduction of beta-enamino ketones | |
dc.type | Artículos de revistas | |