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Additional constraints in adsorption-desorption kinetics
(American Physical Society, 2009-02)
In this work, the adsorption-desorption kinetic in the framework of the lattice gas model is analyzed. The transition probabilities are written as an expansion of the occupation configurations. Due to that, the detail ...
Formic Acid Electrooxidation on Platinum, Resolution of the Kinetic Mechanism in Steady State and Evaluation of the Kinetic Constants
(Wiley Blackwell Publishing, Inc, 2018-09)
A kinetic mechanism recently proposed for the formic acid oxidation (FAO) on platinum in acid solutions was analytically solved in order to verify its capability to correlate experimental measurements in steady state ...
Statistics and kinetics of single-molecule electron transfer dynamics in complex environments: A simulation model study
(American Institute of Physics (AIP), 2008-12-14)
Dynamics of the environments of complex systems such as biomolecules, polar solvents, and glass plays an important role in controlling electron transfer reactions. The kinetics is determined by the nature of a complex ...
Kinetics and Modeling of Fatty Alcohol Ethoxylation in an Industrial Spray Loop Reactor
(WILEY-BLACKWELL, 2011)
The kinetics of the ethoxylation of fatty alcohols catalyzed by potassium hydroxide was studied to obtain the rate constants for modeling of the industrial process. Experimental data obtained in a lab-scale semibatch ...
Electrocatalysis of oxidation of hydrogen on platinum ordered intermetallic phases: Kinetic and mechanistic studies
(Elsevier B.V., 2006-11-08)
An experimentally based kinetic and mechanistic study of the hydrogen oxidation reaction (HOR) on platinum and platinum ordered intermetallic materials in acid medium is presented. RDE kinetic data were re-evaluated and ...
Electrocatalysis of oxidation of hydrogen on platinum ordered intermetallic phases: Kinetic and mechanistic studies
(Elsevier B.V., 2006-11-08)
An experimentally based kinetic and mechanistic study of the hydrogen oxidation reaction (HOR) on platinum and platinum ordered intermetallic materials in acid medium is presented. RDE kinetic data were re-evaluated and ...
Kinetic Modelling of the Photocatalytic Inactivation of Bacteria
(Iwa Publishing, 2010-03)
This work analyzes the kinetic modelling of the photocatalytic inactivation of E. coli in water using different types of kinetic models; from an empirical equation to an intrinsic kinetic model including explicit radiation ...
Modeling the sorption kinetic of metsulfuron-methyl on Andisols and Ultisols volcanic ash-derived soils: Kinetics parameters and solute transport mechanisms
(2010)
Metsulfuron-methyl sorption kinetic was studied in Andisol and Ultisol soils in view of their distinctive physical and chemical properties: acidic pH and variable surface charge. Different kinetic models were applied to ...
Kinetic parameters for thermal decomposition of hydrazine
(2013-09-01)
The propulsion of most of the operating satellites comprises monopropellant (hydrazine - N2H4) or bipropellant (monometilydrazine - MMH and nitrogen tetroxide) chemical systems. When some sample of the propellant tested ...
Kinetic parameters for thermal decomposition of hydrazine
(2013-09-01)
The propulsion of most of the operating satellites comprises monopropellant (hydrazine - N2H4) or bipropellant (monometilydrazine - MMH and nitrogen tetroxide) chemical systems. When some sample of the propellant tested ...