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Living free radical polymerization using cyclic trifunctional initiator
(Wiley-blackwellMaldenEUA, 2012)
Mathematical model for the bulk polymerization of styrene using the symmetrical cyclic trifunctional initiator diethyl ketone triperoxide. I. Chemical initiation by sequential decomposition
(John Wiley & Sons Inc, 2012-03)
In this study, we experimentally and theoretically investigated the use of the symmetrical cyclic trifunctional initiator diethyl ketone triperoxide (DEKTP) in the bulk polymerization of styrene. The experimental study ...
Cyclic Trifunctional Peroxide On Living Free Radical Polymerization
(Italian Association of Chemical Engineering - AIDIC, 2009)
Mathematical Model for the Bulk Polymerization of Styrene Chemically Initiated by Sequential and Total Decomposition of the Symmetrical Cyclic Trifunctional Initiator Diethyl Ketone Triperoxide
(Wiley, 2015-01)
This work experimentally and theoretically investigates the use of the symmetrical cyclic trifunctional initiator diethyl ketone triperoxide (DEKTP) in the bulk polymerization of styrene (St). The study focused on temperatures ...
Mono, Di and Trifunctional Cyclic Organic Peroxides: The Effect of Substituents and Ring Size on their Thermolysis in 1,4-dioxan
(Csiro Publishing, 2013-07-15)
The thermal decomposition reaction of cyclic organic peroxides was studied in 1,4-dioxan at initial concentrations between ~10–4 and 10–2 mol L–1 and at a temperature interval between 100 and 170°C, according to the thermal ...
Bulk Polymerization of Styrene using Multifunctional Initiators in a Batch Reactor: A Comprehensive Mathematical Model
(Berkeley Electronic Press, 2016-01)
A detailed, comprehensive mathematical model for bulk polymerization of styrene using multifunctional initiators – both linear and cyclic – in a batch reactor was developed. The model is based on a kinetic mechanism that ...
Experimental and theoretical study of the use of multifunctional initiators in the high impact polystyrene bulk process
(John Wiley & Sons Inc, 2018-02)
The performance of three multifunctional peroxide initiators in a bulk high impact polystyrene (HIPS) process was experimentally and theoretically investigated. For the experimental work, a series of batch reactions was ...
Bulk hydrosilylation reaction of poly(dimethylsiloxane) chains catalyzed by a platinum salt: Effect of the initial concentration of reactive groups on the final extent of reaction
(John Wiley & Sons Inc, 2003-02-24)
Model silicone networks obtained by curing linear poly(dimethylsiloxane) (PDMS) chains with end-vinyl groups, (B2), with a polyfunctional silane-terminated crosslinker of functionality f, (Af), through a hydrosilylation ...