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Organotellurides as precursors of reactive organometallics
(TAYLOR & FRANCIS LTD, 2008)
Reaction of organotellurides with easily available organometallics leads to a fast and clean tellurium/metal exchange reaction, allowing the preparation of a range of functionalized organometallics with C-sp(3), C-sp(2), ...
Exploring two-state reactivity pathways in the cycloaddition reactions of triplet methylene
(AMER CHEMICAL SOC, 2005-05-12)
Spin forbidden 1,2-cycloadditions of triplet methylene to alkenes have been theoretically studied as an example of the two-state reactivity paradigm in organic chemistry. The cycloadditions of triplet methylene to ethylene ...
Surface organometallic chemistry of vanadium(V): reactivity of (Bu(t)N=)VNp3 towards silica
(Elsevier Science SaLausanneSuíça, 2001)
A simple topology-based model for predicting the activation barriers of reactive processes at 0 K
(Royal Society of Chemistry, 2023-05)
This work reveals an underlying correlation between the topology and energetic features of matter configurations/rearrangements by exploiting two topological concepts, namely, structural stability and persistency, leading ...