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Structure and reactivity of NO/NO+/NO− pincer and porphyrin complexes
(Wiley VCH Verlag, 2021-12)
This review covers recent progress in the field of nitrosyl pincer and porphyrinate complexes, and how their reactivity depends on the redox state of the NO ligand. Synthetic methods, and the most significant structural ...
NO • Disproportionation by a {RhNO} 9 Pincer-Type Complex
(Royal Society of Chemistry, 2017-11)
The reactivity of the {RhNO}9 complex [Rh(PCPtBu)(NO)] (1) with NO was studied. A disproportionation reaction takes place in which N2O is released quantitatively, while the complex Rh(PCPtBu)(NO)(NO2) (2), with coordinated ...
Synthesis, structure and reactivity of NO+, NO• and NO-pincer PCN-Rh complexes
(Royal Society of Chemistry, 2020-05)
Synthesis of a pincer-type linear nitrosyl complex [Rh(PtBu2CNEt2)(NO)]+ (3+ ) is described. The product and all intermediates involved were fully characterized by FTIR, NMR, cyclic voltammetry and X-ray crystallography. ...
Synthesis, structure, and reactivity of nitrosyl pincer-type rhodium complexes
(American Chemical Society, 2009-03)
Pincer-type linear nitrosyl Rh(I) complexes, Rh(PCPBu)(NO)][BF4] (2) and [Rh(PCPBuCH2)(NO)][BF,4] (8), are reported (PCPBu = 1,3-bis[(di-fer/-butylphosphino)methyl]-2,4,6-trimethylbenzene). Complex 2 was synthesized by ...
Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source
(Elsevier, 2017)
Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and
selectivities in the transfer hydrogenation of N-benzylideneaniline using propan-2-ol as the hydrogen source.
Such ...