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Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Wiley, 2010-10)
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic ...
Heterogeneous photochemical reactions of decabromodiphenyl ether
(11/03/2009)
Brominated diphenyl ethers area major class of brominated flame retardants, with production of decabromodiphenyl ether (DBDPE) contributing significantly to this total. Although little is known about the mechanisms and ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
The local and observed photochemical reaction rates revisited
(Royal Society of Chemistry, 2009-06)
In a broad sense, photochemical reactions proceed through pathways involving several reaction steps. The initiation step is the absorption of energy both by the reactant or sensitizer molecules and in some cases, by the ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: dioxygen initiation
(Wiley, 2010-10)
The relevance of radical initiation metodologies for the classical hydrosilylation reactions of organic compounds bearing C[BOND]C multiple bonds is due to the need to come up with newer and more effcient methods to effect ...
Organic synthesis in water mediated by silyl radicals
(Bentham Science Publishers, 2011-06)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...
Photochemical determination of the interactions between surfactants and polyelectrolytes
(1997-04-01)
The interaction of polyelectrolytes with oppositely charged ionic surfactants was studied at low surfactant concentrations using photochemical bound and free probes. Free probes migrate to initially formed pre-aggregates ...
Photochemical determination of the interactions between surfactants and polyelectrolytes
(1997-04-01)
The interaction of polyelectrolytes with oppositely charged ionic surfactants was studied at low surfactant concentrations using photochemical bound and free probes. Free probes migrate to initially formed pre-aggregates ...