The phenolysis of 3-nitrophenyl 4-cyanophenyl thionocarbonate (1) and 4-nitrophenyl 4-cyanophenyl thionocarbonate (2) are subjected to a kinetic investigation in order to evaluate the nucleofugality of the corresponding ...

The phenolysis of 3-nitrophenyl 4-cyanophenyl thionocarbonate (1) and 4-nitrophenyl 4-cyanophenyl thionocarbonate (2) are subjected to a kinetic investigation in order to evaluate the nucleofugality of the corresponding ...

Kinetic and high-performance liquid chromatography studies were investigated for the reactions of S-phenyl, S-(4-chlorophenyl), and S-(4-nitrophenyl) O-(4-nitrophenyl) dithiocarbonates with anilines. These were performed ...

We propose that a specific property of a chemical fragment, its regional electrophilicity, be taken as defining its nucleofugality index nu(PG) in alpha-elimination reactions. We tabulate this quantity for a series of ...

It is proposed that the electrofugality of a fragment within a molecule is determined by its group nucleophilicity. The variation of electrofugality should be tightly related to the electron releasing ability of the ...

It is proposed that the electrofugality of a fragment within a molecule is determined by its group nucleophilicity. The variation of electrofugality should be tightly related to the electron releasing ability of the ...