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Experimental and theoretical studies of the [3,3]-sigmatropic rearrangement of prenyl azides
(Royal Society of Chemistry, 2017-10)
[3,3]-Sigmatropic rearrangement of isoprenyl azides has been extensively investigated in an experimental and theoretical level. Prenylazides with different chain lengths and phenyl prenylazide have been synthesized. NMR ...
Revisiting the Rearrangement of Dewar Thiophenes
(Molecules, 2020)
Mechanistic Insights into a Chiral Phosphoric Acid-Catalyzed Asymmetric Pinacol Rearrangement
(American Chemical Society, 2018-12-01)
The first catalytic enantioselective pinacol rearrangement was reported by Antilla and co-workers in 2010. The reaction was catalyzed by a chiral phosphoric acid and resulted in high levels of enantioselectivity (up to 96% ...
Two state reactivity mechanism for the rearrangement of hydrogen peroxynitrite to nitric acid
(ELSEVIER SCIENCE BV, 2008)
Theoretical Study of the BF3-Promoted Rearrangement of Oxiranyl N-Methyliminodiacetic Acid Boronates
(American Chemical Society, 2017-06)
The mechanism of the rearrangement of oxiranyl N-methyliminodiacetyl (MIDA) boronates in dicholoromethane has been extensively investigated with density functional theory. Several reaction pathways were examined. Our results ...
Insights into the karyotype evolution and speciation of the beetle Euchroma gigantea (Coleoptera: Buprestidae)
(2018-09-01)
Euchroma Dejean, 1833 (Buprestidae: Coleoptera) is a monotypic genus comprising the species Euchroma gigantea, with populations presenting a degree of karyotypic variation/polymorphism rarely found within a single taxonomic ...
Condensed tannin reactivity inhibition by internal rearrangements: Detection by CP-MAS 13C NMR
(Universidad del Bío-Bío, 2011)
Organization and behavior of the synaptonemal complex during achiasmatic meiosis of four buthid scorpions
(Karger, 2014-01-01)
Testicular cells of 4 buthid scorpions, Rhopalurus agamemnon (2n = 28), R. rochai (2n = 28), Tityus bahiensis (2n = 6), and T. fasciolatus (2n = 14), which show different types of chromosomal configurations in meiosis I, ...
Chromothripsis with at least 12 breaks at 1p36.33-p35.3 in a boy with multiple congenital anomalies
(2015-12-01)
Terminal deletion in the short arm of chromosome 1 results in a disorder described as 1p36 deletion syndrome. The resulting phenotype varies among patients including mental retardation, developmental delay, sensorineural ...