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A comparison of charge-transfer mechanisms at rotated disk electrode for biomimetic binuclear and tetranuclear oxo-manganese complex in aqueous solution
(Elsevier B.V., 2015-01-30)
Many high-valence multinuclear mu-oxo-bridged manganese complexes have been synthesized to mimic the active site of the natural enzymes. The electrochemical and kinetic parameters were determined for two mimicking complexes ...
Electrochemical Properties of the Oxo-Manganese-Phenanthroline Complex Immobilized on Ion-Exchange Polymeric Film and Its Application as Biomimetic Sensor for Sulfite Ions
(Wiley-Blackwell, 2014-10-01)
A biomimetic sensor containing the oxo-bridged dinuclear manganese-phenanthroline complex incorporated into a cation-exchange polymeric film deposited onto glassy carbon electrode for detection of sulfite was studied. ...
Electropolymerization mechanism in aqueous solution of the oxo-manganese complex biomimicking of the enzymatic center present on the photosystem II
(2012-12-01)
The [Mn4 IVO5(terpy)4(H 2O)2]6+ complex, show great potential for electrode modification by electropolymerization using cyclic voltammetry. The electropolymerization mechanism was based on the electronic transfer between ...
Electropolymerization mechanism in aqueous solution of the oxo-manganese complex biomimicking of the enzymatic center present on the photosystem II
(2012-12-01)
The [Mn4 IVO5(terpy)4(H 2O)2]6+ complex, show great potential for electrode modification by electropolymerization using cyclic voltammetry. The electropolymerization mechanism was based on the electronic transfer between ...
Voltammetric and spectroscopic study of the manganese-quinizarine-quinaldic acid mixed-ligand complex in dimethylsulfoxide
(PERGAMON-ELSEVIER SCIENCE LTD, 1997)
The combination of manganese(II) with quinizarine and the monoanion of quinaldic acid in dimethylsulfoxide yields a soluble deep-blue complex whose Mn-II:Qz(2-):ACQ(-) stoichiometry is 1:1:2. This complex is oxidized in ...