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Sulfur-hydrogen bond activation of thiols by the fragment CpFe(dppe)+: Cyclopentadienyl iron(III) thiolate complexes
(Elsevier Ltd, 1997)
Oxidative addition of thiols RSH, R = CH3, CH2CH2CH3, CH2C6H5, C(CH3)3 and C6H4Br, by the complex [CpFe(dppe)1] afforded the oxidized thiolate complexes [CpFe(dppe)-SR]PF6. The reaction of [CpFe(dppe)1] with HSC6H4NH2 ...
Observation of stable 17 e iron(III) cyclopentadienyl radical complexes
(Sociedad Chilena de Quimica, 1999)
The EPR spectra of a series of mononuclear complexes [CpFe(dppe)SR]PF6 R = C6H5 (1), C3H7 (2), p-C6H4Br (3) and the binuclear [CpFe(dppe)-S-CH2CH2-S-CpFe(dppe)](PF6) 2 (4) were measured. All the paramagnetic complexes ...
A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
(Sociedad Chilena de Química, 2004)
Reaction of pentacarbonyliron with a nitrogen heterocycle. X-ray crystal structure of bis[(carbonyl)(quinoline-2-thiolate-N,S)]iron(II)
(Elsevier B.V., 1993-02-01)
The monomeric compound bis[(carbonyl)(quinoline-2-thiolate-N,S)]iron(II) was synthesized and studied by IR and Mossbauer spectroscopy, cyclic voltammetry and X-ray diffraction. The molecule has two terminal carbonyl groups ...
S-H bond cleavage in molecules of biological interest with CpFe(dppe)I
(2000)
The reaction of CpFe(dppe)I (Cp, cyclopentadienyl; dppe, Ph2P(CH2)(2)PPh2) with biologically active RSH molecules (L-cysteine hydrochloride, dithiothereitol and 2-mercaptoethanol) in the presence of NH4PF6 and in methanol ...
New entry to piano -stool electron rich (pentamethyl cyclopentadienyl) iron complexes
(Sociedad Chilena de Quimica, 2002)
A new route to the electron rich pentamethylcyclopetadienyl iron complexes (n5-C5Me5)=Cp*) starting from the commercially available dimer [Cp*Fe(CO)2]2, is presented. Reaction of the dimer with I2 in CH2Cl2, affords the ...
Magnetically Assembled SERS Substrates Composed of Iron-Silver Nanoparticles Obtained by Laser Ablation in Liquid
(Wiley VCH Verlag, 2017-05)
The widespread application of surface-enhanced Raman scattering (SERS) would benefit from simple and scalable self-assembly procedures for the realization of plasmonic arrays with a high density of electromagnetic hot-spots. ...
Heme-Thiolate perturbation in cystathionine β-Synthase by mercury compounds
(American Chemical Society, 2021)
Cystathionine β-synthase (CBS) is an enzyme involved in sulfur metabolism that catalyzes the pyridoxal phosphate-dependent condensation of homocysteine with serine or cysteine to form cystathionine and water or hydrogen ...