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Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(Royal Society of Chemistry, 2014)
Solvation effects on the reaction mechanism of the title reactions have been kinetically evaluated in 21 conventional solvents and 17 ionic liquids. Solvent polarity affects the catalyzed and non-catalyzed SNAr pathways ...
Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(Royal Society of Chemistry, 2014)
Solvation effects on the reaction mechanism of the title reactions have been kinetically evaluated in 21 conventional solvents and 17 ionic liquids. Solvent polarity affects the catalyzed and non-catalyzed SNAr pathways ...
A protic ionic liquid, when entrapped in cationic reverse micelles, can be used as a suitable solvent for a bimolecular nucleophilic substitution reaction
(Royal Society of Chemistry, 2016-02)
In this work, we have explored how the confinement of the protic ionic liquid (IL) ethylammonium nitrate (EAN) inside toluene/benzyl-n-hexadecyldimethylammonium chloride (BHDC) reverse micelles (RMs) affects the Cl- ...
Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(ROYAL SOCIETY OF CHEMISTRY, 2014)
Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(ROYAL SOCIETY OF CHEMISTRY, 2014)
Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(ROYAL SOCIETY OF CHEMISTRY, 2014)
Changes in the SNAr reaction mechanism brought about by preferential solvation
(Royal Soc Chemistry, 2015)
We herein report an experimental and theoretical study on preferential solvation effects for the reactions of 1-fluoro and 1-chloro-2,4-dinitrobenzene towards morpholine in acetonitrile, water and mixtures of them of varying ...