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Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: dioxygen initiation
(Wiley, 2010-10)
The relevance of radical initiation metodologies for the classical hydrosilylation reactions of organic compounds bearing C[BOND]C multiple bonds is due to the need to come up with newer and more effcient methods to effect ...
Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2009)
The classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and ...
Water-soluble N-heterocyclic carbene platinum(0) complexes: Recyclable catalysts for the hydrosilylation of alkynes in water at room temperature
(American Chemical Society, 2012-04)
The synthesis and characterization of new water-soluble platinum(0) complexes bearing sulfonated N-heterocyclic carbene (NHC) and divinyltetramethylsiloxane (dvtms) ligands are described. These complexes, of the general ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Wiley, 2010-10)
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic ...
Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
(John Wiley & Sons Inc, 2004-06)
We report preliminary results for the synthesis of poly(ethylene)-graft-poly(dimethylsiloxane) copolymers (PE-g-PDMS) obtained by catalytic hydrogenation of poly(butadiene)-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). ...
Bulk hydrosilylation reaction of poly(dimethylsiloxane) chains catalyzed by a platinum salt: Effect of the initial concentration of reactive groups on the final extent of reaction
(John Wiley & Sons Inc, 2003-02-24)
Model silicone networks obtained by curing linear poly(dimethylsiloxane) (PDMS) chains with end-vinyl groups, (B2), with a polyfunctional silane-terminated crosslinker of functionality f, (Af), through a hydrosilylation ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
Reacciones de Hidrosililación Radicalaria en Agua de Compuestos Orgánicos con Enlaces Agua de Compuestos Orgánicos con Enlaces
(Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales., 2010)
El objetivo del presente trabajo es sintetizar compuestos organosilánicos mediante la hidrosililación radicalaria de compuestos orgánicos con dobles y triples enlaces en agua. Los radicales centrados en
silicio ...
Hydrosilylation of C-C multiple bonds using (Me3Si) 3SiH in water: Comparative study of the radical initiation step
(American Chemical Society, 2009-06)
The classical radical-based hydrosilylation reaction of organic compounds bearing C-C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solventsoluble and water-soluble ...
Polycyclic silicone membranes. Synthesis, characterization and permeability evaluation
(Elsevier Sci LtdOxfordInglaterra, 2001)