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Damping and clustering into crowded environment of catalytic chemical oscillators
(2019-03-01)
A system formed by a crowded environment of catalytic obstacles and complex oscillatory chemical reactions is studied. The obstacles are static spheres of equal radius, which are placed in a random way. The chemical reactions ...
Influence of phase transition on pattern formation during catalytic reactions
(Elsevier, 2000-10)
Influence of phase transition on pattern formation during catalytic reactions
(Physica D: Nonlinear Phenomena, 2000)
Interpretation of the experimental data on the reduction reaction of NO by CO on rhodium by Monte Carlo simulations and by solving the kinetic equations of the reaction mechanism
(AMER CHEMICAL SOC, 2006-04-20)
Some mechanisms of the reduction reaction of NO by CO on rhodium are analyzed and discussed, solving the kinetics equations and using Monte Carlo simulations, in terms of its ability to interpret the recent experiments of ...
Temporal decay of the catalytic oxidation of methane over palladium supported on silica
(Science China Press and Springer, 2013)
The temporal decay of the oxidation of methane (CH4-O2 reaction) over palladium supported on silica is determined experimentally
at different temperatures, comparing the results with those of various classical models which ...
Dba-free palladium intermediates of the Heck-Matsuda reaction
(2013-05-28)
The dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes ...
Dba-free palladium intermediates of the Heck-Matsuda reaction
(2013-05-28)
The dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes ...
Performance of the catalytic membrane reactors of different pore size with palladium as catalytic phase in hydrogenation and oxidation reactions
(2018)
The catalytic membrane reactors (CMR) were prepared using a commercial Hollow Fiber Membrane of corundum of 4 and 1400 nm and impregnated palladium. The tests performed were phenol hydrogenation, hydrogen peroxide generation ...
An Algorithm for Evaluating Reaction Rates of Catalytic Reaction Networks with Strong Diffusion Limitations
(Pergamon-Elsevier Science Ltd, 2001-09)
An h-adaptive mesh procedure to solve the reaction-diffusion problem for multiple reactions in catalytic pellets presenting strong diffusion limitations is developed. The discretization approach selected for this purpose ...