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Oligo- and poly(fullerene)s for photovoltaic applications: Modeled electronic behaviors and synthesis
(2017-04-15)
The atom transfer radical addition polymerization (ATRAP) of fullerene to give poly(fullerene)s (PFs) for organic electronics is explored. Quantum chemistry maps the expected electronic behavior of PFs with respect to ...
Simulation Of Temperature Effect On The Structure Control Of Polystyrene Obtained By Atom-transfer Radical Polymerization
(Associação Brasileira de PolÃmerosSão Carlos, 2016)
From one-pot stabilisation to in situ functionalisation in nitroxide mediated polymerisation: An efficient extension towards atom transfer radical polymerisation
(Royal Society of Chemistry, 2012-07-03)
A one-pot controlled method for the nitroxide end-group removal from synthetic polymers prepared by nitroxide mediated polymerisation (NMP) is reported. The strategy relies on the controlled addition of compounds such as ...
Atom Transfer Radical Polymerization of Methyl Methacrylate Mediated by Grubbs 1st and 2nd Generation Catalysts: Insight into the Active Species
(Soc Brasileira Quimica, 2017-01-01)
Ruthenium benzylidene complexes were evaluated as catalysts in atom-transfer radical polymerization (ATRP) of methyl methacrylate (MMA) under different reaction conditions. The mechanism by which Grubbs 1st and 2nd generation ...
Simulation of the Equilibrium Constant Effect on the Kinetics and Average Properties of Polystyrene Obtained by ATRP
(Soc Brasileira QuimicaSao PauloBrasil, 2013)
In Situ Generation of Fullerene from a Poly(fullerene)
(2019-11-01)
This article appraises the thermal, photo- and photo-oxidative stability of poly(fullerene)-alt-[bismethylbenzene)]s (PFBMBs) prepared by the atom transfer radical addition polymerization (ATRAP) with particular attention ...
Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
(Elsevier, 2021)
This work reports the synthesis of poly (monomethyl itaconate) grafted multi-layer graphene oxide (PMMI-g-GO) by atom transfer radical polymerization using activators regenerated by electron transfer (ARGET-ATRP). PMMIg-GO ...
Electrophoretic separation of proteins on capillary columns grafted with non-fouling, stable films prepared by controlled radical polymerization [recurso electrónico]
(2019-10-09)
Proteins are complex macromolecules that are inherently active towards a variety of surfaces. The active sites of the surface can enable structural alteration and destabilization of many proteins leading to their adsorption. ...