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Unique magnetic shielding and bonding in Pnicogen nortricyclane Zintl clusters
(Chemical Physics Letters, 2020)
Spherical Aromaticity of All-Metal [Bi@In8Bi12]3−/5− Clusters
(Wiley-VCH Verlag, 2020)
[Cp*RuPb11]3−and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra
(Royal Society of Chemistry, 2020-09-21)
Cluster anions [Cp*RuPb11]3−(1) and [Cu@Cp*RuPb11]2−(2) represent the first vertex-substituted zintl icosahedra and1is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes1and2are both ...
Eclipsed- and staggered-[ge18pd3{e'pr-3}(6)](2-) (e = si, sn): positional isomerism in deltahedral zintl clusters
(2017)
We report the synthesis and characterization of the cluster anions [Ge18Pd3{Si`Pr-3}(6)]2-(1) with a core of face fused twinned icosahedra, Ge18Pd3, and two sets of three 'Pr3Si-substituents positioned in "eclipsed" geometry. ...