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Volcano plots in hydrogen electrocatalysis: uses and abuses
(Beilstein-Institut, 2014-06)
Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A ...
Testing Reactivity Descriptors for the Electrocatalytic Activity of OPG Hybrid Electrodes Modified with Iron Macrocyclic Complexes and MWCNTs for the Oxidation of Reduced Glutathione in Basic Medium
(Springer Nature, 2019)
In this work we have tested the Fe(III)/(II) redox potential of the catalysts as a reactivity descriptors of iron macrocyclic complexes (FeN4) adsorbed on multi-walled carbon nanotubes (MWCNTs) and deposited on ordinary ...
Mapping experimental and theoretical reactivity descriptors of fe macrocyclic complexes deposited on graphite or on multi walled carbon nanotubes for the oxidation of thiols: Thioglycolic acid oxidation
(2021)
We have studied the electro-oxidation of thioglycolic acid (TGA) catalyzed by iron phthalocyanines and iron porphyrins (FeN4 complexes) deposited on ordinary pyrolytic graphite and on multiwalled carbon nanotubes. The ...
Oxygen Reduction Reaction at Penta-Coordinated Co Phthalocyanines
(Frontiers Media S.A., 2020-01)
From the early 60s, Co complexes, especially Co phthalocyanines (CoPc) have been extensively studied as electrocatalysts for the oxygen reduction reaction (ORR). Generally, they promote the 2-electron reduction of O2 to ...
Bajo la sombra del volcán. Aproximaciones al cine de catástrofesUnder the shadow of the volcano. Approaches to the cinema of catastrophe
(Secretaría de Posgrado, Universidad Nacional de Quilmes, 2020)