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Stereoselective Synthesis of Stannyl Enones via Palladium-Catalyzed and Free Radical Hydrostannation of Alkynyl Ketones with Trineophyltin Hydride
(American Chemical Society, 2003-12)
A study on the addition of trineophyltin hydride (1) to alkynones under free radical (AIBN and Et3B) and palladium-catalyzed [(PPh3) 2PdCl2] conditions is reported. The results obtained indicate that the addition of 1 to ...
Palladium-catalyzed stereoselective hydrostannation of substituted propargyl alcohols with trineophyltin hydride
(Elsevier Science Sa, 2008-05)
This paper reports results obtained in a study on the palladium-catalyzed hydrostannation of substituted propargyl alcohols with the bulky trineophyltin hydride (1). The reaction of 1 with 10 propargyl alcohols containing ...
Stereoselective hydrostannation of substituted alkynes with trineophyltin hydride
(Elsevier Science Sa, 2002-05)
Hydrostannation of mono- and disubstituted alkynes with trineophyltin hydride (1) leads to vinylstannes in good to excellent yields the configuration of the products depending on the reaction conditions. Thus, whereas ...
Bicyclic allyltin derivatives through selective "one pot" hydrostannation - Diels-Alder reaction
(Arkat, 2011-02)
In this paper we report a simple "one pot" procedure to functionalized allyltin derivatives from 1- ethynylcyclohexene. Radical addition of trineophyltin hydride gives quantitatively to (Z,E)-1-(2- trineophylstannylvinyl ...