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Recent advances in the synthesis of stannanes and the scope of theirposterior chemical transformations
(Elsevier Science Sa, 2014-01)
The SRN1 reactions of trimethylstannyl and triphenylstannyl anions, and other tin nucleophiles with haloarenes are quite versatile. Thus, the SRN1 mechanism can afford triorganylstannyl aromatic compounds which otherwise ...
Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
(Teknoscienze Publisher, 2011-06)
Since arsines are drawing particular attention as ligands in metal-catalyzed reactions, the development of new methods to obtain organoarsines is increasingly recognized as central in the synthesis of new ligands. Transition ...
Highly efficient palladium-catalyzed arsination. Synthesis of a biphenyl arsine ligand and its application to obtain perfluoroalkylarsines
(American Chemical Society, 2009-12)
An efficient one-pot, two-step Pd-catalyzed arsination with n-Bu 3SnAsPh2 (1) and sterically hindered aryl iodides (ArI) with different functional groups is reported. The cross-coupling reactions of this stannane with ArI ...