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Combined experimental and theoretical studies on the radical nucleophile addition reaction for Sulfide- and Selenide-Centered Anions
(American Chemical Society, 2019-06)
The reactivity of sulfur- and selenium-centered nucleophiles toward 1-naphthyl radicals was studied in dimethylsulfoxide. The photostimulated reaction of sulfide anions, -SC(NH)C6H5 (1), -SC(NH)NH2 (2), and -SC(NH)CH3 (3), ...