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Role of Ruthenium Oxidation States in Ligand-to-Ligand Charge Transfer Processes

Ramirez, Cristina Lujan; Pegoraro, César Nicolás; Filevich, Oscar; Bruttomesso, Andrea; Etchenique, Roberto Argentino; Parise, Alejandro Ruben (American Chemical Society, 2012-01)

We describe in this paper the properties of [RuII/III(bpy)2ClL]+1/+2 and [RuII/III(bpy)2L2]+2/+3. L = ditolyl-3-pyridylamine (dt3pya) is a redox active ligand related to triarylamines, which is very similar to 3-aminopyridine ...