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On-line generation of third-order liquid chromatography–excitation-emission fluorescence matrix data. Quantitation of heavy-polycyclic aromatic hydrocarbons
(Elsevier Science, 2017-12)
For the first time, third-order liquid chromatography with excitation-emission fluorescence matrix detection (LC-EEFM) data were generated on-line and chemometrically processed for the simultaneous quantitation of the ...
Analytical chemistry assisted by multi-way calibration: A contribution to green chemistry
(Elsevier Science, 2019-11-01)
A review is presented of recent multi-way calibration protocols involving three-, four- andfive-way data. A brief description of the various data structures and processing models isshown, with emphasis on model selection ...
Excitation-emission fluorescence-kinetic data obtained by Fenton degradation. Determination of heavy-polycyclic aromatic hydrocarbons by four-way parallel factor analysis
(Elsevier Science, 2017-04)
For the first time, a simple and environmentally friendly third-order/four-way calibration was applied for the simultaneous determination of five heavy-polycyclic aromatic hydrocarbons (PAHs) in interfering environments. ...
Critical evaluation of third-order advantage with highly overlapped spectral signals. Determination of fluoroquinolones in fish-farming waters by fluorescence spectroscopy coupled to multivariate calibration
(2019)
In this work, the analytical performance of a third-order/four-way calibration is evaluated to model a highly overlapped system, where two spectral dimensions are extremely similar, and the results are then compared with ...
A review on second- and third-order multivariate calibration applied to chromatographic data
(Elsevier Science, 2012-02)
Quantitative analytical works developed by processing second- and third-order chromatographic data are reviewed. The various modes in which data of complex structure can be measured are discussed, with chromatographic ...
Chemometric modeling of kinetic-fluorescent third-order data for thiamine determination in multivitamin complexes
(Elsevier Science, 2016-03)
Thiamine (vitamin B1) was converted into a fluorescent thiochrome by oxidation catalyzed by Hg2+ in alkaline medium. The kinetic evolution for this conversion was followed by emission-excitation spectroscopy generating a ...
Online Third-Order Liquid Chromatographic Data with Native and Photoinduced Fluorescence Detection for the Quantitation of Organic Pollutants in Environmental Water
(American Chemical Society, 2018-11)
Third-order liquid chromatographic data were generated online for the simultaneous quantitation of six organic environmental pollutants. The employed strategy consists in reducing the linear flow rate at the column outlet. ...