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Sulfur-hydrogen bond activation of thiols by the fragment CpFe(dppe)+: Cyclopentadienyl iron(III) thiolate complexes
(Elsevier Ltd, 1997)
Oxidative addition of thiols RSH, R = CH3, CH2CH2CH3, CH2C6H5, C(CH3)3 and C6H4Br, by the complex [CpFe(dppe)1] afforded the oxidized thiolate complexes [CpFe(dppe)-SR]PF6. The reaction of [CpFe(dppe)1] with HSC6H4NH2 ...
Selective nanomechanics of aromatic versus Aliphatic Thiolates on Gold Surfaces
(American Physical Society, 2019-02)
Thiolated gold nanointerfaces play a key role in numerous fields of science, technology, as well as modern medicine to coat, functionalize, and protect. Our computational study reveals that the mechanical vs thermal ...
ENCAPSULATION OF LEU-ENKEPHALIN IN CORE-SHELL ISOBUTYLCYANOACRYLATE - THIOLATED CHITOSAN NANOPARTICLES FOR ORAL ADMINISTRATION
(Sociedad Chilena de Química, 2008)
Anti-mycobacterium tuberculosis and cytotoxicity activities of ruthenium(II)/Bipyridine/Diphosphine/Pyrimidine-2-thiolate complexes: The role of the non-coordinated n-atom
(2016-01-01)
The [Ru(Spym)(bipy)(P-P)]PF6, [Spym = pyrimidine-2-thiolate anion; P-P = 1,2-bis(diphenylphosphino)ethane, 1,3-bis(diphenylphosphino)propane and 1,1'-bis(diphenylphosphino)ferrocene] complexes were synthesized and characterized ...
A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
(Sociedad Chilena de Química, 2004)
Double-Tagging Polymerase Chain Reaction with a Thiolated Primer and Electrochemical Genosensing based on Gold Nanocomposite Sensor for Food Safety
(Amer Chemical Soc, 2009-02-15)
A novel material for electrochemical biosensing based on rigid conducting gold nanocomposite (nano-AuGEC) is presented. Islands of chemisorbing material (gold nanoparticles) surrounded by nonreactive, rigid, and conducting ...
Double-Tagging Polymerase Chain Reaction with a Thiolated Primer and Electrochemical Genosensing based on Gold Nanocomposite Sensor for Food Safety
(Amer Chemical Soc, 2009-02-15)
A novel material for electrochemical biosensing based on rigid conducting gold nanocomposite (nano-AuGEC) is presented. Islands of chemisorbing material (gold nanoparticles) surrounded by nonreactive, rigid, and conducting ...
Stretching of BDT-gold molecular junctions: thiol or thiolate termination?
(Royal Soc Chemistry, 2014-01-01)
It is often assumed that the hydrogen atoms in the thiol groups of a benzene-1,4-dithiol dissociate when Au-benzene-1,4-dithiol-Au junctions are formed. We demonstrate, by stability and transport property calculations, ...
Observation of stable 17 e iron(III) cyclopentadienyl radical complexes
(Sociedad Chilena de Quimica, 1999)
The EPR spectra of a series of mononuclear complexes [CpFe(dppe)SR]PF6 R = C6H5 (1), C3H7 (2), p-C6H4Br (3) and the binuclear [CpFe(dppe)-S-CH2CH2-S-CpFe(dppe)](PF6) 2 (4) were measured. All the paramagnetic complexes ...
Cyclic voltammetric and scanning electrochemical microscopic study of thiolated beta-cyclodextrin adsorbed on a gold
(AMERICAN CHEMICAL SOCIETY, 2003)