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Determination of chemical rate constants in singlet molecular oxygen reaction by using 1,4-dimethylnaphthalene endoperoxide
(2002)
Thermal decomposition of 1,4-dimethylnaphthalene endoperoxide (DMNE) as a source of singlet oxygen was used to measure chemical rate constants, k(R), for reactions between singlet oxygen, O-2((1)Delta(g)), and various ...
Spin effects in oxygen electrocatalysis: a discussion
(Elsevier Science, 2013-04)
The reduction of molecular oxygen in triplet and singlet spin states at metal electrodes is analyzed in the framework of quantum mechanical theory of charge transfer. Both outer- and inner-sphere mechanism is considered. ...
ON THE USE OF 9,10-DIMETHYLANTHRACENE AS CHEMICAL RATE CONSTANT ACTINOMETER IN SINGLET MOLECULAR OXYGEN REACTIONS
(Sociedad Chilena de Química, 2000)
A non-singlet oxygen mediated reaction photoinduced by phenalenone, a universal reference for singlet oxygen sensitization
(Royal Society of Chemistry, 2014-02)
Photosensitized oxidations involve the generation of radicals (type I mechanism) and/or the production of singlet molecular oxygen (1O2) (type II mechanism). Phenalenone (PN) is one of the well-known type II photosensitizers ...
Acetazolamide as a singlet molecular oxygen quencher
(Elsevier Science, 2013-08)
According to literature the acetazolamide, which is commonly used as a diuretic, shows phototoxic properties. To contribute to the understanding of the role of this chemical as a generator of the very common toxic substance, ...
Solvent effects on reactions of singlet molecular oxygen, O2(1Δg), with antimalarial drugs
(2004)
Detection of O2(1Δg) emission, λmax=1270 nm, following laser excitation and steady-state methods were employed to measure total reaction rate constants, k T, for the reaction between singlet oxygen and the antimalarial ...
Two phenothiazine dyes as photosensitizers for the production of singlet oxygen. Photophysics, photochemistry and effects of aggregation
(Elsevier Science, 2019-04)
The aim of this work was to investigate the aggregation effect of Azure B and monobrominated Azure B on their singlet oxygen generation. The monomeric and dimeric forms of these dyes were evaluated to select the species ...
Solvent effect on the sensitized photooxygenation of cyclic and acyclic alpha-diimines
(PERGAMON-ELSEVIER SCIENCE LTD, 2006-11-13)
The reaction of singlet molecular oxygen with a series of cyclic and acyclic alpha-diimines was studied. Time-resolved methods were used to measure total reaction rate constants and steady-state methods were used to determine ...