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Organic synthesis in water mediated by silyl radicals
(Bentham Science Publishers, 2011-06)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...
Organic Synthesis in Water Mediated By Silyl Radicals
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2011)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...
(Me3Si)3SiH-mediated intermolecular radical perfluoroalkylation reactions of olefins in water
(American Chemical Society, 2010-09)
Figure presented. Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Wiley, 2010-10)
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
Photochemical generation of siliconcentered radicals and their reactions
(Nova Science Publishers, 2008)
This chapter is organized according to classes of silicon-containing compounds that giverise to silyl-centered radicals through photolytic methods, then reviewing their reactivity,their spectroscopic data, and their possible ...
Photochemical Generation of Silicon-centered Radicals and their Reactions
(Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación, 2008)
This chapter is organized according to classes of silicon-containing compounds that give
rise to silyl-centered radicals through photolytic methods, then reviewing their reactivity,
their spectroscopic data, and their ...
Monolayers and Thin Films of Dextran Hydrophobically Modified
(SOC BRASILEIRA QUIMICA, 2010)
A series of biodegradable graft copolymers were synthesized by grafting epsilon-caprolactone over dextran of different molecular weights. The obtained copolymers were characterized by Fourier transform infrared spectroscopy ...
(Me3Si)3SiH-Mediated Intermolecular Radical Perfluoroalkylation Reactions of Olefins in Water
(Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved through different ...
Rat ventral prostate xanthine oxidaseg-mediated metabolism of acetaldehyde to acetyl radical
(Sage Publications Ltd, 2009-04)
Alcohol drinking is known to lead to deleterious effects on prostate epithelial cells from humans and experimental animals. The understanding of the mechanisms underlying these effects is relevant to intraprostatic ethanol ...