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Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine
(2011)
2-Ferrocenyl-1,8-naphthyridine (1) and cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, 1H-NMR spectroscopy and elemental analysis. ...
Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands
(2010)
The synthesis and characterization of new ruthenium(II) carbonyl complexes containing polypyridine and triphenylphosphine ligands is reported. Crystallographic information obtained for the trans-PPh3-[Ru(biq) (PPh3)2(CO)]Cl2 ...
Ruthenium(II)-carbonyl complexes containing two N-monodentate 1,8-naphthyridine ligands: active catalysis in transfer hydrogenation reactions
(Wiley-Blackwell, 2018)
The reaction of 2-aminonicotinaldehyde with 2- or 4-methoxyacetophenone in basic media leads to the new ligands 2-(4-methoxyphenyl)-1,8-naphthyridine and 2-(2-methoxyphenyl)-1,8-naphthyridine, respectively, in high yield. ...
Ruthenium (II) complexes in catalytic oxidation
(2001)
Ruthenium (II) complexes of the type RuL(CO)(2)Cl-2, [RuL(CO)(2)L-2'](2+) and [RuL(CO)(2)Cl L'](+) [L=bipyridine (bpy), phenanthroline (phen), biquinoline (biq) and L'=pyridine (py), 4-chloropyridine (Cl-py), 4-methoxypyridine ...
Transient photocyclization in ruthenium(II) polypyridine complexes of indolamines
(Royal Society of Chemistry, 2016-12)
Ruthenium polypyridine complexes have proved to be useful caging groups for visible-light photodelivery of biomolecules. In most photoreactions, one ligand is expelled upon irradiation, yielding ruthenium mono-aqua complexes ...
Benzonitrile hydrolysis catalyzed by a ruthenium(II) complex
(Taylor & Francis Ltd, 2002-07)
The rate constant for the basic hydrolysis of benzonitrile (PhCN) to benzamide (PhCONH2) in the [RuII(tpy)(bpy)] moiety (tpy = 2,2′:6′,2″-terpyridine, bpy = 2,2′-bipyridine) (kOH = 3.7 × 10-2 M-1s-1) is 5 × 103 times higher ...
Structural, electronic, and thermochemical preference for multi-PCET reactivity of ruthenium(II)-amine and ruthenium(IV)-amido complexes
(Wiley VCH Verlag, 2021-10-21)
The multiredox reactivity of bioinorganic cofactors is often coupled to proton transfers. Here we investigate the structural, thermochemical, and electronic structure of ruthenium-amino/amido complexes with multi- ...