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Influence of polymerization conditions on the molecular weight and polydispersity of polyepichlorohydrin
(Pergamon-elsevier Science LtdOxfordInglaterra, 2007)
Ring-opening polymerization of ε-caprolactone by iodine charge-transfer complex
(John Wiley & Sons Inc, 2002-12)
The ring-opening polymerization of ε-caprolactone (ε-CL) catalyzed by iodine (I2) was studied. The formation of a charge-transfer complex (CTC) among triiodide, I3-, and ε-CL was confirmed with ultraviolet-visible spectroscopy. ...
Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates
(Csiro Publishing, 2016-07-12)
Ring-opening homo- and co-polymerization reactions of ε-caprolactone were performed by employing anionic polymerization (high vacuum techniques) and lithium silanolates (LS) as initiators. LS were obtained by reaction ...
Microwave-assisted polymer synthesis (MAPS) as a tool in biomaterials science: How new and how powerful
(Pergamon-Elsevier Science Ltd, 2011-08)
Lack of reproducibility, difficult and expensive scale-up and standarization of synthetic processes are the main hurdles towards the industrial production of raw synthetic and semi-synthetic polymers for (bio)pharmaceutical ...
e-Caprolactone / ZnCl2 complex formation: characterization and ring-opening polymerization mechanism
(John Wiley & Sons Inc, 2000-03-09)
ε-Caprolactone (ε-CL) has been mixed with ZnCl2 at different mol ratios. The resulting complex was characterized through 1H and 13C NMR spectroscopy in bulk and in solutions, differential scanning calorimetry (DSC), ...
Intrinsic self-initiating thermal ring-opening polymerization of 1,3-benzoxazines without the influence of impurities using very high purity crystals
(John Wiley & Sons Inc, 2017-10)
A phenol/aniline type monofunctional benzoxazine monomer, PH-a, is synthesized and highly purified to study the intrinsic thermal ring-opening polymerization of benzoxazines without the influence of any impurity. The ...