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Electrochemical triggered O-atom transfer reaction in nitrocarbonyl rhenium(I) complexes: An IR spectroelectrochemical investigation
(Elsevier, 2015-07-11)
In previous work we proposed that polypyridylrhenium(I)tricarbonyl complexes coordinated to ion nitrite through its N-atom in CH2Cl2 solution could give nitrosyl complexes by electrochemical oxidation. In this work, we ...
Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
(Elsevier Science, 2014-11-05)
We report here the infrared and Raman spectra of [Re(CN)5NO]3- complex as guest diluted in the KCl crystal lattice. According to the chemical analysis, the anion concentration in the KCl host matrix is in excess of 2% (in ...
Photoinduced linkage isomerization in new rhenium(I) tricarbonyl complexes coordinated to N-nitrite and O-nitrite
(Elsevier, 2013-10)
The ambidentate nitrite ion, NO2−, is a biologically relevant species that can be coordinated to transition metals via the nitrogen or oxygen atom. Most of its physiological effects involve metalloproteins so it is important ...
Synthesis, structure, and reactivity of (η5:η1-C5Me4(CH2)2NMe2)Re(CO)2. Electron transfer behavior of a nitrosyl derivative
(Elsevier Science Sa, 2014-05)
The UV irradiation of a hexane solution of the complex (h5 -C5Me4(CH2)2NMe2)Re(CO)3 (1) afforded the chelated species (h5 :h1 -C5Me4(CH2)2NMe2)Re(CO)2 (2). The molecular structure of 2 has been determined by X-ray ...
Synthesis, structure, and reactivity of (n5:n1-C5Me4(CH2)2NMe2) Re(CO)2. Electron transfer behavior of a nitrosyl derivative
(Elsevier, 2014)
The UV irradiation of a hexane solution of the complex (n5-C5Me4(CH2)2NMe2)Re(CO)3 (1) afforded the
chelated species (n5:n1-C5Me4(CH2)2NMe2)Re(CO)2 (2). The molecular structure of 2 has been determined
by X-ray ...