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High energy density MnO4-/MnO42- redox couple for alkaline redox flow batteries
(Royal Society of Chemistry, 2016)
The MnO4-/MnO42- redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature. Careful optimization of the electrolyte composition and the potential ...
Redox-Driven Reversible Gating of Solid-State Nanochannels
(American Chemical Society, 2019-08)
The design of an electrochemically addressable nanofluidic diode is proposed, which allows tunable and nanofluidic operations via redox gating under electrochemical control. The fabrication process involves the modification ...
Three Redox States of Nitrosyl: NO+, NO., and NO-/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform
(Wiley VCH Verlag, 2009-05)
Not so elusive: [FeII(CN)5(HNO)]3- has been characterized spectroscopically after the two-electron reduction of nitroprusside (see scheme). The complex is stable at pH 6, slowly decomposing to [Fe(CN)6]4- and N2O. It is ...
Reversible redox modifications of ryanodine receptor ameliorate ventricular arrhythmias in the ischemic-reperfused heart
(American Physiological Society, 2016)
Previous results from our laboratory showed that phosphorylation of ryanodine receptor 2 (RyR2) by Ca2+ calmodulin-dependent kinase II (CaMKII) was a critical but not the unique event responsible for the production of ...
Redox modulation of plant developmental regulators from the class I TCP transcription factor family
(American Society of Plant Biologist, 2013-07)
TEOSINTE BRANCHED1-CYCLOIDEA-PROLIFERATING CELL FACTOR1 (TCP) transcription factors participate in plant developmental processes associated with cell proliferation and growth. Most members of class I, one of the two classes ...
Reversible Switching of Redox-Active Molecular Orbitals and Electron Transfer Pathways in CuA Sites of Cytochrome c Oxidase
(Wiley VCH Verlag, 2015-08)
The CuA site of cytochromec oxidase is a redox hub that participates in rapid electron transfer at low driving forces with two redox cofactors in nearly perpendicular orientations. Spectroscopic and electrochemical ...