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Using theoretical calculations to predict the redox potential of mononuclear manganese complexes
(Royal Society of Chemistry, 2018-09)
The rational design of biomimetic complexes of metalloenzymes involved in redox processes is of great interest in bioinorganic chemistry. Its purpose is to utilize the redox properties of mimics and use them as redox-active ...
Mercury Redox Chemistry in the Negro River Basin, Amazon: The Role of Organic Matter and Solar Light
(Springer, 2010-03-01)
Pristine water bodies in the Negro River basin, Brazilian Amazon, show relatively high concentrations of mercury. These waters are characterized by acidic pH, low concentrations of suspended solids, and high amounts of ...
Can electrophilicity act as a measure of the redox potential of first-row transition metal ions?
(WILEY-V C H VERLAG GMBH, 2007)
Previous contributions concerning the computational approach to redox chemistry have made use of thermodynamic cycles and Car-Parrinello molecular dynamics simulations to obtain accurate redox potential values, whereas ...
High energy density MnO4-/MnO42- redox couple for alkaline redox flow batteries
(Royal Society of Chemistry, 2016)
The MnO4-/MnO42- redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature. Careful optimization of the electrolyte composition and the potential ...
Redox and complexation chemistry of the Cr(VI)/CR(V) –D-galacturonic acid system
(2004)
The oxidation of d-galacturonic acid by Cr(VI) yields the aldaric acid and Cr(III) as final products when a 30-times or higher excess of the uronic acid over Cr(VI) is used. The redox reaction involves the formation of ...
Capacitance Spectroscopy: A Versatile Approach To Resolving the Redox Density of States and Kinetics in Redox-Active Self-Assembled Monolayers
(Amer Chemical Soc, 2012-08-02)
Redox active self-assembled monolayers inherently possess both electrochemically addressable and polarizable components. The latter will contribute, with additional parasitic terms, to the iR drop effects within any form ...
Capacitance Spectroscopy: A Versatile Approach To Resolving the Redox Density of States and Kinetics in Redox-Active Self-Assembled Monolayers
(Amer Chemical Soc, 2012-08-02)
Redox active self-assembled monolayers inherently possess both electrochemically addressable and polarizable components. The latter will contribute, with additional parasitic terms, to the iR drop effects within any form ...
Elucidating Redox-Level Dispersion and Local Dielectric Effects within Electroactive Molecular Films
(Amer Chemical Soc, 2014-02-18)
The electron exchange between a redox-active molecular film and its underlying electrode can be cleanly tracked, in a frequency-resolved manner, through associated capacitive charging. If acquired data is treated with a ...