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Synthetic Organometallic Radical Chemistry in Water
(Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación, 2009)
Several organic radical transformations in aqueous media using organometallic chemistry are presented. Group XIV-elements, such as Si and Ge, and Sn-centered radicals make use of novel methodologies in water which employ ...
Reactivity of fluorinated organic radicals in aqueous media
(Wiley VCH Verlag, 2012-04)
Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl ...
Streamlining free radical green chemistry
(Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación, 2012)
This practical and concise guide showcases the sustainable methods offered by green free radical chemistry and summarizes the fundamental science involved. It discusses free radical chemistry in aqueous systems for synthetic ...
Photochemical Generation of Silicon-centered Radicals and their Reactions
(Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación, 2008)
This chapter is organized according to classes of silicon-containing compounds that give
rise to silyl-centered radicals through photolytic methods, then reviewing their reactivity,
their spectroscopic data, and their ...
(Me3Si)3SiH-mediated intermolecular radical perfluoroalkylation reactions of olefins in water
(American Chemical Society, 2010-09)
Figure presented. Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved ...
Synthetic organometallic radical chemistry in water
(Bentham Science Publishers, 2009-04)
Several organic radical transformations in aqueous media using organometallic chemistry are presented. Group XIV-elements, such as Si and Ge, and Sn-centered radicals make use of novel methodologies in water which employ ...
Radical Based Arylation Methods
(Wiley, 2009)
Most of the radical reactions can be conducted under mild conditions. In contrast to ionic reactions and many transition-metal mediated processes most of the functional groups are tolerated under radical conditions. Moreover, ...
Thermal degradation of chalcogenides containing poly(methacrylates)
(1990)
Thermogravimetric analysis of aromatic poly(methacrylates) containing heterocyclic side chains were carried out. The effect of the substituent introduced into the side chain on the thermal stability of the polymer was ...
Radical Arylations
(John Wiley & Sons Ltd, 2012)
This chapter reports on radical arylations also highlighting the very important early achievements on this chemistry. To be named at this place are the Meerwein arylation and the Pschorr reaction. Intramolecular homolytic ...
The ORAC (oxygen radical absorbance capacity) index does not reflect the capacity of antioxidants to trap peroxyl radicals
(Royal Society of Chemistry, 2015)
© The Royal Society of Chemistry 2015.In the present work we demonstrate from kinetic studies that under the experimental conditions proposed for the ORAC protocol, ORAC values do not correlate with the capacity of ...