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Spectroscopic signatures of ligand field states in {RuII(imine)} complexes
(Royal Society of Chemistry, 2016-04)
Ligand field (LF) states have been present in discussions on the photophysics and photochemistry of ruthenium-iminic chromophores for decades, although there is very little documented direct evidence of them. We studied ...
Four chromophores in one building block: Synthesis, structure and characterization of trans -[Ru(MQ)4Cl2]4+ and trans -[Ru(4,4-bpy)4Cl2] (MQ+ = N-methyl-4,4-bipyridinium, bpy = bipyridine)
(Taylor & Francis Ltd, 2015-02)
We report the synthesis, crystal structure, electrochemical and spectroscopic properties of trans-[Ru(MQ)4Cl2]4+ (14+), where MQ+ = N-methyl-4,4′-bipyridinium. The crystal structure of 14+ shows the pyridinic rings bound ...