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Diolefin rhodium(I) complexes with tropolone and related ligands
(1981)
Rhodium(I) tropolonate and salicylaldehydate complexes of the general formula Rh(A)(diolefin) (A = tropolonate, ?-iso-propyltropolonate, ?-methyltropolonate and salicylaldehydate; diolefin = 1,5-cyclooctadiene, 2,5-norbornadiene ...
NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS
(Sociedad Chilena de Química, 2007)
REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
(Sociedad Chilena de Química, 2005)
Rhodium(I) complex with hexylamine and chloride ligands, catalytically active in the selective hydrogenation of 1-heptyne
(American Chemical Society, 2006-08)
A rhodium(I) complex containing chloro and hexylamine was obtained. This species shows catalytic activity for the 1-heptyne semihydrogenation under at mild conditions (303 K and 150 kPa) in homogeneous as well as heterogeneous ...
Group VIII transition metal complexes with the chiral diphosphazane ligand (S)-alpha-(Ph2P)(2)N(CHMePh): Synthesis and structural characterization
(ELSEVIER SCIENCE SA, 2006)
The chiral ligand S-(Ph2P)(2)N(CHMePh) reacts with Ni(CO)(4) in benzene solution to yield the mononuclear complex [Ni(CO)(2)]{kappa(2)-(PPh2)2N(CHMePh))] (1). The reactions of the chiral ligand with the solvated complexes ...
MaxPHOS Ligand: PH/NH Tautomerism and Rhodium- Catalyzed Asymmetric Hydrogenations
(Wiley VCH Verlag, 2014-03)
MaxPHOS is an active and robust P-stereogenic ligand for asymmetric catalysis. The presence of an NH bridge between the two phosphine moieties allows the NH/PH tautomerism to take place. The neutral ligand, in which the ...
Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes
(1983)
The preparation and properties of cationic rhodium(I) complexes of the types [Rh(Me3TFB)L2]PF6 (L=O. N. P, As or Sb-donor ligands, Me3TFB=trimethyltetrafluorobarrelene), [Rh(Me3TFB) (?6-arene)]PF6 (arene=C6Me6, C6H6Me3, ...
Rhodium(I) diolefin complexes with polycyclic π-arene ligands. Synthesis of bimetallic complexes with diphenylmethane as bridging ligand
(1984)
The preparation and properties of cationic arenerhodium(I) complexes of general formula [Rh(diolefin)(?6arene)]ClO4 (diolefin=1,5-cyclooctadiene, tetrafluorobenzobarrelene or trimethyltetrafluorobenzobarrelene; arene = ...
Hydrogen transfer reactions catalyzed by neutral rhodium(I) Schiff base complexes
(1984)
Hydrogen transfer reactions from 2-propanol to acetophenone or cyclohexene are catalyzed by neutral rhodium(I) complexes of the type [Rh(COD)L] and [Rh2(COD)2L'] (where L and L' are Schiff base ligands and COD=cycloocta- ...