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Controlled One-Pot Synthesis of Polystyrene-block-Polycaprolactone Copolymers by Simultaneous RAFT and ROP
(Wiley, 2013-08)
A convenient one-pot method for the controlled synthesis of polystyrene- block -polycaprolactone (PS- b -PCL) copolymers by simultaneous reversible addition?fragmentation chain transfer (RAFT) and ring-opening polymerization ...
Thermal Characterization of “Comb-Like” Block Copolymers Based on PCL Obtained by Combining ROP and RAFT Polymerizations
(Wiley, 2016-10-21)
In this work we report the synthesis of poly(hydroxyethylmethacrylate-graft-polycaprolactone)-block-poly(caprolactone) copolymers,P(HEMA-g-PCL)-b-PCL, by combining ring-opening polymerization (ROP)and reversible ...
Synthesis of Grafted Block Copolymers Based on e-Caprolactone: Influence of Branches on Their Thermal Behavior
(Wiley Vch Verlag, 2015-11-17)
Branched copolymers are a special class of polymeric materials in which are refl ected the combined effects of polymer segments and architectural constraints of the branched architecture. This study employed two methodologies ...
Facile one-pot synthesis and solution behavior of poly(acrylic acid)-block-polycaprolactone copolymers
(Elsevier Science, 2019-01)
A metal-free protocol to obtain poly(acrylic acid)-block-polycaprolactone diblock copolymers (PAA-b-PCL) by a one-pot method involving simultaneous Reversible Addition-Fragmentation Chain Transfer (RAFT) and Ring Opening ...
Tailor-made, linear, and “comb-like” polyester-based copolymers: Synthesis, characterization, and thermal behavior of potential 3D-printing/electrospinning candidates
(Hindawi Publishing Corporation, 2018-10)
Tailor-made, linear, and “comb-like” poly(ε-caprolactone)-based copolymers were synthesized by employing a combination of controlled polymerization techniques. Poly(dimethylsiloxane-block-ε-caprolactone) copolymers (SCL#) ...
Composite coatings based on linear and branched block copolymers for hydroxyapatite deposition in simulated body-fluid
(Taylor & Francis, 2020-01)
In this work, the fabrication of composite coatings based on block copolymers and silicates deposited on stainless-steel plates through electrophoretic deposition technique was studied. Linear poly(ɛ-caprolactone), and ...
Síntesis y caracterización de copolímeros bloque biocompatibles
(2018-04-04)
La polimerización aniónica es una de las vías sintéticas para obtener macromoléculas con estructuras bien definidas y mínima heterogeneidad. Mediante el correcto empleo de esta técnica es posible obtener homo y copolímeros ...