Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl ...

This chapter reports on radical arylations also highlighting the very important early achievements on this chemistry. To be named at this place are the Meerwein arylation and the Pschorr reaction. Intramolecular homolytic ...

Flusilazole is an organosilane fungicide used for treatments in agriculture and horticulture for control of diseases. The reaction kinetics and mechanism of flusilazole with sulfate and hydroxyl radicals were studied. The ...

Photoinitiated perfluorobutylation reactions of 2-anisidine 1, propenyloxybenzene 2, and 2-mercaptoethanol 3 have been carried out employing commercially available n-C4F9I as the source of C4F9 radicals under three different ...

The mechanism of the addition reaction of TeCl(4) to alkynes was indirectly established by the detection of TeCl(3) centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization. Crown Copyright (C) 2008 ...

The relevance of radical initiation metodologies for the classical hydrosilylation reactions of organic compounds bearing C[BOND]C multiple bonds is due to the need to come up with newer and more effcient methods to effect ...

The reactions of 2-(4-Z-phenyl)-1,3-dithiane anions (Z=H, OMe, Cl, CN) with neopentyl, neophyl and phenyl iodides were studied in DMSO, taking into consideration the effect of the Z substituent on the dithiane anions ...

Accurate dynamic mechanical measurements were performed on poly(monocyclohexyl itaconate) at different frequencies over a wide temperature range. Three main relaxations could be observed at different temperatures, which ...