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Facilitated proton transfer reactions via water autoprotolysis across oil|water interfaces. Half-wave potential
(Pergamon-Elsevier Science Ltd, 2020-02)
The main purpose of this paper is to develop the equations for the half-wave potentials of facilitated proton transfer or protonated species transfer across liquid|liquid interfaces, explicitly considering the water ...
Facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2017-12)
The theory of cyclic voltammetry of facilitated proton transfer-electron transfer coupled reactions (FPT-ET reactions) in a thick organic film modified electrode is developed. It is shown that the coupling between the ...
Multidimensional redox potential/pKacoupling in multicopper oxidases from molecular dynamics: implications for the proton transfer mechanism
(2021-12-28)
Bilirubin oxidases (BOD) are metalloenzymes that catalyze the conversion of O2and bilirubin to biliverdin and water in the metabolism of chlorophyll and porphyrin. In this work we have used the CpHMD method to analyze the ...
Effect of ligand protonation on the facilitated ion transfer reactions across oil|water interfaces. V. Applications of forced hydrodynamic conditions
(Elsevier Science Sa, 2016-03-05)
Hydrodynamic forced conditions applied to the aqueous or the organic phase during a potential sweep can be used to elucidate themechanisms of ion transfer across liquid|liquid interfaces. The aimof this study is to confirm ...
Design and synthesis of benzimidazole phenol-porphyrin dyads for the study of bioinspired photoinduced proton-coupled electron transfer
(World Sci Publ Co Inc, 2019-09)
Benzimidazole phenol-porphyrin dyads have been synthesized to study proton-coupled electron transfer (PCET) reactions induced by photoexcitation. High-potential porphyrins have been chosen to model P680, the photoactive ...
An integrated theoretical-experimental approach to understand facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2018-09)
The main purpose of the current work is to generalize the analytical model for the facilitated proton transfer-electron transfer coupled reactions at thick organic film-modified electrodes, including ion pairing in the ...
Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires
(Royal Society of Chemistry, 2020-03)
Designing molecular platforms for controlling proton and electron movement in artificial photosynthetic systems is crucial to efficient catalysis and solar energy conversion. The transfer of both protons and electrons ...
Controlling proton-coupled electron transfer in bioinspired artificial photosynthetic relays
(American Chemical Society, 2018-10)
Bioinspired constructs consisting of benzimidazole-phenol moieties bearing N-phenylimines as proton-accepting substituents have been designed to mimic the H-bond network associated with the TyrZ-His190 redox relay in ...