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Coordinating properties of some solvents in Cr(CO)5L complexes
(1988)
The influence of the donor-acceptor properties of several solvents on the Cr(CO)5 group in the solid [Cr(CO)5·solvent] complexes has been examined by spectroscopic methods. Relationships were found between the acceptor ...
New complexes [CpFe(dppe)thiophenes]PF6
(Elsevier Ltd, 1996)
The reactions of CpFe(dppe)I with thiophenes in the presence of T1PF6 afforded the new complexes [CpFe(dppe)thiophenes]PF6 (thiophenes = thiophene, 2-methyl-thiophene, 3-methyl-thiophene, 2,5-dimethyl-thiophene, benzothiophene ...
Ionization of the FeX bond in polar solvents: A spectroscopic study of CpFe(dppe)X complexes
(1993)
Electronic absorption spectra for complexes CpFe(dppe)X [with X = Cl, I and CN; dppe = (Ph)2PCH2CH2P(Ph)2; Cp = η5-C5H5] and the cationic derivative [CpFe(dppe)NCCH3]PF6 in different solvents have been measured. The lower ...
Ion-pairing and optical activity of diastereomeric zinc(II) 1, 10-phenanthroline, S-valinate systems
(1983)
A series of S-valinatobis(1, 10-phenanthroline)zinc salts in methanolic solution have been prepared and their conductivities and ORD spectra measured. A positive linear correlation of optical rotation with conductance was ...
Sulfur(II)-metal coordination compounds. Group VI metal carbonyl complexes with N,N′-thiobisamines ligands
(1984)
The novel complexes M(CO)5S(NR2)2 (M = Cr, Mo or W) have been prepared by the addition of N,N′-thiobisamine (NR2 = dimethylamine, piperidine, morpholine or dibenzylamine) to UV-irradiated tetrahydrofuran solutions of M(CO)6. ...
Sulphurating and coordinating properties of N,N′-thiobismorpholine towards iron carbonyls
(1990)
The reactions of N,N′-thiobismorpholine, {A figure is presented}, with Fe(CO)5, Fe2(CO)9, Fe3(CO)11 and [(η5-C5H5)Fe(CO)2THF]BF4 were examined. Thiobismorpholine undergoes desulphurization towards Fe(CO)5 with formation ...
Conformation and optical activity of copper(II) complexes with L-aminoacids in the visible region
(1976)
The Cotton effect of dd transitions of copper(II) complexes with optically active aminoacids in aqueous media is qualitatively analyzed in terms of conformational models by means of a simple one-electron MO treatment. The ...
Rede de conhecimento em estequiometria: produção de animações e simulações em laboratório virtual como facilitador do ensino-aprendizagem em química
(Universidade Tecnológica Federal do ParanáPato BrancoBrasilUTFPR, 2014)
An interactive guide with animations created from adobe flash professional program (swf) contains scripts that will allow chemistry students carrying out experiments in a virtual laboratory using the experimental simulation ...