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Structural and electronic effects on the exchange interactions in dinuclear bis(phenoxo)-bridged copper(II) complexes
(Elsevier, 2010)
Computational methods based on density functional theory have been employed to analyze the magnetic properties of dinuclear bis(phenoxo)-bridged CuII complexes. While the largest part of complexes in that family show ...
Copper(II) complexes with new polypodal ligands presenting axial-equatorial phenoxo bridges {2-[(Bis(2-pyridylmethyl)amino)methyl]-4-methyl phenol, 2-[(Bis(2-pyr1dylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol}: Examples of ferromagnetically coupled
(2007)
Two new ligands, 2-[(bis(2-pyridylmethyl)amino)methyl]-4-methylphenol (HL) and 2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol (HSL), were synthesized and were used to prepare the trinuclear copper(II) ...
Tuning the MnII 2/MnIII 2 redox cycle of a phenoxo-bridged diMn catalase mimic with terminal carboxylate donors
(Elsevier Science Inc, 2018-05)
A new phenoxo-bridged diMnIII complex, Na[Mn2L(OH)2(H2O)2]·5H2O (1), obtained with the ligand L5− = 5‑methyl‑2‑hydroxo‑1,3‑xylene‑α,α‑diamine‑N,N,N′,N′‑tetraacetato, has been prepared and characterized. Mass spectrometry, ...
Tuning White Light Emission in Dinuclear Phenoxo Bridged DyIII Complexes
(American Chemical Society, 2019)
© 2019 American Chemical Society.A new series of dinuclear dysprosium(III) complexes, [Dy2(LCH3)2(NO3)2(MeOH)2] (I), [Dy2(LCH3)2(NO3)2(DMF)2]·2DMF (II), [Dy2(LCl)2(NO3)2(DMF)2]·2DMF (III), and [Dy2(LCH3O)2(NO3)2(DMF)2] ...
Enhancement of Terbium(III)-Centered Luminescence by Tuning the Triplet Energy Level of Substituted Pyridylamino-4-R-Phenoxo Tripodal Ligands
(American Chemical Society, 2020)
A series of luminescent phenoxo-bridged dinuclear Tb-III complexes with tripodal ligands, 2,2'4 [(2-pyridinylmethyl)-imino]di(methylene)]-bis(4-R-phenol), where R = CH3 (L-CH3) (I), Cl (L-Cl) (II), CH3O (L-CH3O) (III), ...
The templating effect of halides in the tetrameric copper(II) [Cu 2(LH)2(μ4-X)Cu2(LH) 2]3+ complexes (LH2 = N-(2-pyridylmethyl)-N,N- bis-[2′-hydroxy-5′-methyl-benzyl]-amine; X = Br, Cl). Synthesis and magneto-structural characterization
(Elsevier Ltd, 2014)
The synthesis, magnetic and structural characterization of two tetrameric copper(II) complexes {N(C4H9)4}-[Cu 2(LH)2(μ4-Br)Cu2(LH) 2](PF6)4 (1) and [Cu2(LH) 2(μ4-Cl)Cu2(LH)2](Cl) 2(PF6) (2) is described. LH stands for the ...
Copper(II) complexes with new polypodal ligands presenting axial-equatorial phenoxo bridges {2-[(Bis(2-pyridylmethyl)amino)methyl]-4-methyl phenol, 2-[(Bis(2-pyr1dylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol}: Examples of ferromagnetically coupled Bi- and trinuclear copper(II) complexes
(AMER CHEMICAL SOC, 2007-08)
Two new ligands, 2-[(bis(2-pyridylmethyl)amino)methyl]-4-methylphenol (HL) and 2-[(bis(2-pyridylmethyl)amino)methyl]-
4-methyl-6-(methylthio)phenol (HSL), were synthesized and were used to prepare the trinuclear copper(II) ...
Dinuclear cobalt(III) and mixed valence trinuclear Mn-III-Mn-II-Mn-III complexes with a tripodal bridging pyridylaminophenol ligand
(Royal Society of Chemistry, 2016)
A dinuclear cobalt(II), [Co2(kappa(4)-O,O', N,N'-L)(2)(mu-O,O'-HCOO)](ClO4)center dot(C2H5)(2)O (1) and a linear mixed valence trinuclear manganese, [Mn-3(kappa(4)-O,O', N,N'-L)(2)(mu-CH3O)(2)(mu-O,O'-CH3COO)(2)]center dot ...
Structural Characterization of Iron(iii) Dinuclear Complexes
(2014)
Dinuclear complexes have been studied for different purposes: magnetic materials[1], Non-linear optics materials[2], molecular
switches [3], mixed-valence systems, etc. With these antecedents in mind, we present in this ...