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19F chemical shifts, coupling constants and conformational preferences in monosubstituted perfluoroparacyclophanes
(John Wiley & Sons Ltd, 2011-02)
In the process of studying the chemistry of perfluoro[2.2]paracyclophanes (PFPCs), a novel class of compounds, it became necessary to identify some disubstituted products. To achieve this goal, we characterize in this work ...
[2.2]Paracyclophane-4,7,12,15-tetrone, [2.2](1,4)naphthalenophane-4,7,14,17-tetrone, and 1,4,8,11-pentacenetetrone radical anions - A comparative ESR study
(Wiley-VCH Verlag, 1998)
Three types of tetrone radical anions in which two 1,4-benzoquinone units are connected by ethano (1·-, 2·-), [2.2]paracyclophane (3·-, 4·-), and anthracene bridges (5·-, 6·-) have been studied by ESR and ENDOR spectroscopy. ...
Behavior of [2.2]paracyclophane in magnetic fields: a survey of the magnetic response properties from chemical shift tensor maps
(ELSEVIER SCIENCE PUBLISHERS B.V., 2011)
[2.2.2]paracyclophane, preference for eta(6) or eta(18) coordination mode including ag(i) and sn(ii): a survey into the cation-pi interaction nature through relativistic dft calculations
(2015)
[2.2.2] Paracyclophane is a versatile pi-cryptating structure, which can exhibit eta(2):eta(2):eta(2) and eta(6):eta(6):eta(6) coordination with metal ions, involving two or six carbon atoms in each aromatic ring. According ...
[2.2.2]Paracyclophane, preference for η6 or η18 coordination mode including Ag(I) and Sn(II) : A survey into the cation-π interaction nature through relativistic DFT calculations
(2015)
[2.2.2]Paracyclophane is a versatile π-cryptating structure, which can exhibit η2:η2:η2 and η6:η6:η6 coordination with metal ions, involving two or six carbon atoms in each aromatic ring. According to the nature of the ...
Influence of ag+ on the magnetic response of [2.2.2]paracyclophane: nmr properties of a prototypical organic host for cation binding based on dft calculations
(2015)
The complexation of metal cations into a host-guest situation is particularly well exemplified by [2.2.2]paracyclophane and Ag-I, which leads to a strong cation-pi interaction with a specific face of the host molecule. ...
Role of the cation formal charge in cation-pi interaction. A survey involving the [2.2.2]paracyclophane host from relativistic dft calculations
(2015)
The foie of the metal formal charge in the cation-pi interactions has been evaluated with relativistic DFT methods involving a versatile pi-cryptating structure, namely [2.2.2]paracyclophane. Our study focuses on experimentally ...