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Organometallic Chalcones Functioning as Radical Traps: Observations on the Solvated Electron Reduction and the C center dot H2OH and C center dot H2Cl Addition Processes. A Time-Resolved, Mechanistic Study
(2016)
The pulse radiolysis method was used to investigate reactions between organometallic chalcones derived from ferrocene, cyrhetrene, and cymantrene substituted with a phenyl (R-1) or a 4'-benzo-15-crown-5 (B-1) moiety and ...
Novel organometallic chalcones functionalized with a crown ether fragment as optical ion chemosensors
(2018)
We previously reported the synthesis and characterization of new organometallic chalcones derived from ferrocene, cyrhetrene and cymantrene functionalized with a benzo-15-crown-5 fragment. The ferrocene and cyrhetrene ...
Synthesis and characterization of organometallic chalcones functionalized with a crown ether fragment. Spectroscopic and electrochemical behavior
(2017)
Organometallic chalcone complexes functionalized with a macrocyclic fragment [(eta(5)-C5H4C(O)CH=CH-4-benzo-15-crown-5)MLn] (ferrocenyl, cyrhetrenyl, and cymantrenyl) have been synthesized. The complexes are characterized ...
Kinetic and Mechanistic Observations on the Photoinduced Isomerization Reaction of Organometallic Chalcones: A Steady State and Flash Photolysis Study
(2018)
The photoinduced isomerization (E to Z) processes of a new series of organometallic chalcones derived from cyrhetrene, ferrocene and cymantrene functionalized with a benzo or 4-benzo-15-crown-5 moiety were studied in ...
On the photochemical properties of the organometallic trans cyrhetrenyl chalcone (E). Deceleration of the photoisomerization and quenching of the luminescence effected by the photogenerated cis isomer (Z)
(2018)
The photoprocesses of two organometallic chalcone complexes: one trans (E) [(eta(5)-C5H4C(O)CH = CH-Ph) Re(CO)(3)], (1a), and the other functionalized with a macrocyclic trans (E) [(eta(5)-C5H4C(O)CH = CH-4-benzo-15-crown-5) ...