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A family of ruthenium complexes containing the non-innocent ligand o-benzoquinonediimine. An infrared structural interpretation
(2003)
It has been shown that innocent ligands always contribute with a similar electron density to a metal centre in a complex regardless of which other innocent ligands are bonded to the same centre, while non-innocent ligands ...
A FAMILY OF RYTHENIUM COMPLEXES CONTAINING THE NON-INNOCENT LIGAND O-BENZOQUINONEDIIMINE: AN INFRARED STRUCTURAL INTERPRETATION
(Sociedad Chilena de Química, 2003)
METAL COMPOUNDS OF THE TCNX REDOX SYSTEMS -FROM ELECTRON TRANSFER TO SPIN DISTRIBUTION AND MAGNETISM
(Sociedad Chilena de Química, 2008)
Preparation, characterization and structure of ruthenium phosphine complexes containing non-innocent ligands
(PERGAMON-ELSEVIER SCIENCE LTDOXFORD, 2012)
Phosphine ruthenate complexes containing the non-innocent ligands 4-chloro-1,2-phenylenediamine (opda-CI) and 3,3',4,4'-tetraamminebiphenyl (diopda) were synthesized and characterized by means of X-ray diffraction, ...
On the non-innocence and reactive: Versus non-reactive nature of α-diketones in a set of diruthenium frameworks
(Royal Society of Chemistry, 2021-01)
α-Diketones are an important class of building blocks employed in many organic synthetic reactions. However, their coordination chemistry has rarely been explored. In light of this, our earlier report on [(acac)2RuII(μ-2 ...
Non-innocent Behavior Of 1-(2'-pyridylazo)-2-naphtholate Coordinated To Polypyridine Ruthenium(ii) Complexes
(Taylor and Francis Ltd., 2014)
Kinetic and structural studies of aldehyde oxidoreductase from Desulfovibrio gigas reveal a dithiolene-based chemistry for enzyme activation and inhibition by H2O2
(Public Library of Science, 2013-12-31)
Mononuclear Mo-containing enzymes of the xanthine oxidase (XO) family catalyze the oxidative hydroxylation of aldehydes and heterocyclic compounds. The molybdenum active site shows a distorted square-pyramidal geometry in ...
Investigação inédita da atividade de complexos mononucleares de FeIII na hidrólise de ésteres de fostato
(2019)
Hidrolases sintéticas chamam a atenção por sua potencial aplicação como medicamentos antitumorais e antibióticos. Atualmente, objetiva-se o desenvolvimento de modelos mais eficientes e, principalmente, seletivos na clivagem ...
An amine linker group modulates luminescent properties in a Rhenium(I) tricarbonyl complex. How can it be applied for ratiometric oxygen sensing?
(Elsevier, 2020-01)
The UV–Vis absorption spectrum of the rhenium(I) tricarbonyl complex [(NH2-phen)Re(CO)3Br] (ReNN-NH2Br, a deep-orange solid) in solution shows three bands located at 300, 370 and 445 nm. TD-DFT calculations and spectroscopic ...
Estudo computacional do óxido nítrico em solução: dinâmica molecular, potenciais de redução e fotoliberação por complexos de ru-nitrosil
(Universidade Federal de Minas GeraisUFMG, 2017-04-19)
During the last three decades, much eort has been devoted to understanding biological processes in which Nitric Oxide (NO) is involved. This interest is justied by the various biological functions attributed to this molecule, ...